Advanced Nanocomposites Research Articles

Green Synthesis and Enhanced Photocatalytic Performance of rGO/ZnO/Fe3O4 Nanocomposites: A Sustainable Approach to Environmental Remediation.

The fast industrialization and mounting pollution have necessitated the need for advanced materials in order to degrade pollutants efficiently. Metal oxide-based and graphene-derivative photocatalytic nanocomposites are excellent for harnessing light energy in environmental remediation. Among them, ZnO-based nanocomposites have drawn considerable attention because of their high photocatalytic activity and stability. However, improving the performance of these nanocomposites is still necessary for their wide applications. This study explores the green synthesis, detailed characterization, and enhanced photocatalytic efficiency of reduced graphene oxide rGO/ZnO/Fe3O4 nanocomposites. The nanocomposites were synthesized via a hydrothermal method, utilizing milk thistle extract as a natural reducing agent, representing a novel and sustainable approach to fabricating magnetic rGO/Fe3O4 nanocomposites. These composites were further integrated with zinc oxide to produce a multifunctional material, exhibiting high surface area, superior electrical and thermal conductivity, and robust mechanical strength. The photocatalytic performance was significantly enhanced due to the synergistic interaction between graphene and metal oxide nanoparticles, leading to efficient degradation of environmental pollutants. Electrochemical analysis via cyclic voltammetry revealed distinctive redox peaks, demonstrating efficient electron transfer processes essential for applications in energy conversion and storage. This green synthesis not only provides a sustainable pathway for the development of advanced nanocomposites but also underscores their potential in a wide range of applications, including environmental remediation, sensing, energy storage, and optoelectronics.

An Extensive Study of Metal Matrix Composites and their Various Properties for Different Uses

This study examines the creation and development of composite materials, from conventional techniques to their innovative uses in numerous industries. Composite materials that are robust, versatile, and resilient have advanced significantly, especially with the application of nanotechnology and hybrid fiber reinforcements. Composite materials are difficult to machine due to their anisotropic and non-homogeneous structure, as well as the high abrasiveness of their reinforcing parts. This typically results in the workpiece becoming damaged and the cutting tool wearing down very rapidly. On composite materials, traditional machining methods such as turning, drilling, and milling can be applied with the appropriate tool design and operating parameters. An overview of the various issues related to the conventional machining of the main types of composite materials is given in this work. This article examines novel matrix materials, forms of reinforcement, and production procedures to show how advanced metallic matrix nano composites and fiber-reinforced polymers are replacing traditional composites. Special emphasis is given to the strict manufacturing conditions in addition to the homogenous dispersion of nanoparticles and damage-free machining of fiber composite materials. The essay also discusses how sustainable alternatives, including reinforcements made of natural fibers, affect the ecosystem. This study aims to offer a comprehensive analysis and case studies.

Artificial neural network-enhanced mathematical simulation based on Carrera unified formulation for dynamic analysis and structural integrity assessment of advanced nanocomposites reinforced tunnel structures

This article presents the application of the Carrera Unified Formulation (CUF) for dynamic analysis and structural integrity assessment of advanced nanocomposite-reinforced tunnel structures. CUF offers a generalized framework that simplifies the modeling of complex structures, providing an efficient approach to address the dynamic behavior of nanocomposites. Advanced nanocomposites, which enhance mechanical performance and durability, are increasingly used in critical infrastructure such as tunnel systems. Traditional methods often fall short in capturing the intricate interactions within these materials, particularly under dynamic loads. CUF overcomes these challenges by incorporating higher-order theories and multi-scale analysis, allowing for accurate prediction of displacements, stresses, and potential failure modes. To further validate the results, an Artificial Neural Network (ANN) model is trained using simulated data, ensuring robust predictions for various loading conditions. The ANN assists in approximating the dynamic response and integrity of the structure, enabling real-time assessments with minimal computational expense. The combined CUF-ANN approach demonstrates high accuracy and efficiency, making it a reliable tool for the structural integrity assessment of nanocomposite-reinforced tunnels. This study highlights the significant potential of integrating CUF and ANN for the analysis and design of advanced engineering structures subjected to dynamic environmental conditions.

Photosensitizer conjugated carbon dots@dopamine-copper sulfide nanocomposites: Advanced photoactive agents for antibacterial applications through experimental and theoretical insights

The massive use and abuse of antibiotics has given birth to drug-resistant bacteria and emergence of severe bacterial infections in people. Intriguingly, light activated antimicrobial activity i.e. antimicrobial photodynamic therapy has gained enhanced therapeutic potential and efficacy in killing the bacterial cells. Therefore, the present study investigates the efficacy of employing advanced nanocomposites for biocidal inhibition of bacterial growth through enhanced sterilization capabilities. Specifically, dopamine functionalized CuS NPs combined with carbon dots (CDs@Dop-CuS) were selected for their remarkable photodynamic potential when used in conjunction with methylene blue (MB). Comparative and synergistic application of Dop-CuS, CDs, and MB revealed the superior singlet oxygen generation potency of MB/CDs@Dop-CuS. Furthermore, the structural changes in the E. coli bacterial cells membrane were elucidated through scanning electron microscopy imaging, demonstrating superior inhibition rates of MB/CDs@Dop-CuS compared to MB alone under 660 nm irradiation. The commendable docking score and binding potential of CDs@Dop-CuS nanocomposites obtained via molecular docking simulations further validate their efficacy as photosensitizers against E. coli bacterial cells. Thus, this novel MB/CDs@Dop-CuS photosensitizer provides enhanced efficacy as an alternative to traditional antibiotic treatments, offering a superior disinfection for public utility services and addressing the growing issue of drug-resistant bacterial infections.

Enhanced performance of GO and RGO/Y2SiO5: Sm3+ nanocomposites for supercapacitors and biosensors

The increasing demand for high-performance materials in energy storage and biosensing applications highlights the need for ongoing research. Traditional materials often fail to meet the required standards for specific capacitance, energy density, and selectivity. Developing advanced nanocomposites, such as reduced graphene oxide (RGO) based Y2SiO5:Sm3+ (RYSOS), seeks to overcome these limitations, providing enhanced efficiency and stability. This study synthesized RYSOS nanocomposites for supercapacitor and biosensor applications, demonstrating superior performance over graphene oxide (GO) (GYSOS). RYSOS exhibited a higher specific capacitance of 474.81 Fg−1 compared to 396.68F−1 for GYSOS, and an energy density of 55.55 Wh/kg versus 32.89 Wh/kg. Additionally, RYSOS electrodes showed improved capacity retention at 87.83 % and coulombic efficiency at 91.54 % after 5000 cycles. In biosensing, RYSOS-modified carbon paste electrodes achieved excellent dopamine detection at pH 7.4, with a limit of detection (LOD) of 0.8579 µM and a limit of quantification (LOQ) of 2.859 µM. The developed electrode also demonstrated high selectivity for dopamine over uric acid and maintained 90 % stability over 10 cycles. These findings underscore the potential of RYSOS nanocomposites in enhancing the performance of advanced energy storage systems and biosensors, highlighting their effectiveness in specific capacitance, energy density, and selective biosensing capabilities.

Synthetic vs. natural antimicrobial agents for safer textiles: a comparative review.

Textiles in all forms act as carriers in transmitting pathogens and provide a medium of microbial growth, especially in those fabrics which are used in sports, medical and innerwear clothing. More attention towards hygiene and personal healthcare made it a necessity to develop pathogen-free textiles. Synthetic and natural antimicrobial compositions are used to control and reduce microbial activity by killing or inhibiting microbial growth on textiles. Synthetic metallic nanoparticles of Ag, Zn, Cu Ti and Ga are the most commonly and recently used advanced nanocomposites. Synthetic organic materials such as triclosan, quaternary ammonium compounds, polyhexamethylene biguanide, and N-halamines have proven antimicrobial activity. Carbon quantum dots are one of the advanced nanomaterials prepared from different kinds of organic carbon material with photoluminescence efficiency also work efficiently in antimicrobial textiles. A greener approach for producing natural antimicrobial textiles has gained significant importance and demand for personal care due to their less toxic effects on health and the environment In comparison to synthetic. The naturally existing materials including extracts and essential oils of plants have significant applications for antimicrobial textiles. Additionally, a number of animal extracts are also used as antimicrobial agents include chitosan, alginate, collagen hydrolysate to prepare naturally treated antimicrobial textiles. This review focuses on the comparative performance of antimicrobial fabrics between synthetic and natural materials. Textiles with synthetic substances cause health and environmental concerns whereas textiles treated with natural compositions are more safe and eco-friendly. Finally, it is concluded that textiles modified with natural antimicrobial compositions may be a better alternative and option as functional textiles.

Harnessing potential of microwave-assisted ultrafast synthesis of reduced graphene oxide/Mn3O4 bioactive nanocomposite hydrogel for bone tissue engineering

The development of functional materials with the potential for bone tissue regeneration along with rapid synthesis and cost-effective approach has been challenging. In this regard, hydrogels have been explored as a potent candidate to behave as a 3D scaffold for bone repair. However, poor mechanical attributes impeded their clinical translation. Enthralling demonstration of the potential of carbon-based nanocomposites in bone tissue engineering has been constantly encouraging the fabrication of advanced nanocomposites. Here, we investigated the fabrication of reduced graphene/manganese (II, III) oxide (RGO/Mn3O4) nanocomposites by taking advantage of the microwave-assisted synthesis approach for cost effective, and ultrafast synthesis. Mn3O4 nanoparticles with uniform distribution in RGO sheets and ∼ 1.7 nm size was fabricated using the approach. Further, fine-tuning of the structural interaction and mechanical behavior of the GelMA-based hydrogels upon reinforcement with RGO/Mn3O4 nanocomposites was investigated as a function of different concentrations of the nanocomposites where upto 50 % increment in the compressive stress was observed compared to native GelMA hydrogel. The ability of these hydrogels was further investigated for their osteogenic behaviour on MC3T3-E1 preosteoblast cells where constant cell proliferation for up to 10 days was witnessed for the hybrid hydrogel with the highest concentration of the nanofillers.

Click-Chemistry-Enabled Functionalization of Cellulose Nanocrystals with Single-Stranded DNA for Directed Assembly.

Controlling the self-assembly of cellulose nanocrystals (CNCs) requires precise control over their surface chemistry for the directed assembly of advanced nanocomposites with tailored mechanical, thermal, and optical properties. In this work, in contrast to traditional chemistries, we conducted highly selective click-chemistry functionalization of cellulose nanocrystals with complementary DNA strands via a three-step hybridization-guided process. By grafting terminally functionalized oligonucleotides through copper-free click chemistry, we successfully facilitated the assembly of brushlike DNA-modified CNCs into bundled nanostructures with distinct chiral optical dichroism in thin films. The complexation behavior of grafted DNA chains during the evaporation-driven formation of ultrathin films demonstrates the potential for mediating chiral interactions between the DNA-branched nanocrystals and their assembly into chiral bundles. Furthermore, we discuss the future directions and challenges that include new avenues for the development of functional, responsive, and bioderived nanostructures capable of dynamic reconfiguration via selective complexation, further surface modification strategies, mitigating diverse CNC aggregation, and exploring environmental conditions for the CNC-DNA assembly.

Highly functionalized all-cellulose nanocomposites via bacteria-enabled in-situ modifications

Bacterial cellulose (BC) is an appealing class of nanoscale biopolymers with immense potential for sustainable development across food, energy, and health sectors. However, facile, green approaches to convert BC into functional, value-added materials remain limited. Here, novel BC nanocomposites are developed by incorporating highly functional amorphous cellulose chains, called “hairs”. It is shown how in-situ modifications via integrating hairy nanocrystalline cellulose (HNCC) into cellulose-synthesizing Komagataeibacter medellinensis media enable all-cellulose nanocomposites with diverse functional groups. As a result, sterically stabilized HNCC (SNCC) with neutral aldehyde, electrosterically stabilized HNCC (ENCC) with carboxyl and bifunctional HNCC (BNCC) with both aldehyde-carboxyl groups yield hairy BC/SNCC (aldehyde ∼ 0.9 mmol g−1), BC/ENCC (carboxyl ∼ 1.5 mmol g-1) and BC/BNCC (aldehyde ∼ 0.8 mmol g-1 and carboxyl ∼ 1.1 mmol g-1) nanocomposites, respectively. These nanocomposites, characterized by finely tuned chemistry and architecture, offer versatile sustainable platforms. Anionic BC/ENCC and BC/BNCC are loaded with the antibacterial ɛ-poly-L-lysine (PLL) to explore drug adsorption isotherms, release kinetics, and underlying mechanisms. The antibacterial efficacy of hairy nanocomposites is quantified, followed by a biocompatibility assessment with human bone marrow stromal cells (hBMSC). This work lays the foundation for BC conversion to highly functional advanced nanocomposites for a wide range of applications.

Sequential-dependent synthesis of gold-chromium nanocomposites for multimode colorimetric sensing, advanced logic computing, and tri-layer information protection

Binary materials combine the properties and advantages of their components, but their fabrication paradigm needs updating to fully exploit their characteristics and broaden their application. Here, multifunctional bimetallic gold-chromium nanocomposites (Au–Cr NCs) were synthesized facilely in a sequential-dependent manner, and applied from multi-channel sensing to molecular informatization (including advanced logic computing and tri-layer information protection). By sequentially mixing Cr6+, Au3+, and NaBH4 (reducing agent), Au–Cr NCs with Au nanoparticles attached to Cr nanobelts can be prepared easily and quickly. The resulting Au–Cr NCs exhibited multi-signal sensing capability for hypochlorite, with significantly improved selectivity (about 5 times) and sensitivity (about 1650 times) when analyzing multiple signals. The synthesis process can be used to implement parallel molecular logic gates and customizable keypad lock operations. Moreover, by digitizing logical relationships and multimodal selective responses based on Au–Cr NCs, specific information (wise sayings and literary works sentence) can be encoded, encrypted and hidden to realize nano-cryptography and steganography. When combined with molecular keypad lock, a tri-layer information protection system can be constructed to enhance anti-cracking ability. This study promotes controllable preparation and multi-purpose applications of advanced multifunctional nanocomposites, but also opens up a new direction for nano-based sensing and digitization in multi-dimension.

Guided wave propagation in a high-speed rotating concrete shell reinforced by advanced nanocomposites

This paper investigates the propagation of guided waves in a high-speed rotating concrete shell reinforced with graphene oxide powders (GOP) using higher-order shear deformation theory (HSDT). The study addresses the complexities introduced by initial hoop tension and provides a comprehensive analytical solution procedure. Concrete shells are widely used in various engineering applications due to their robustness and durability; however, their mechanical performance can be significantly enhanced by the incorporation of GOP, which improves the material properties, such as tensile strength and modulus of elasticity. The analysis begins with the formulation of the governing equations based on HSDT, which accurately captures the effects of transverse shear deformation and rotary inertia, crucial for high-speed rotating structures. The presence of initial hoop tension, resulting from the centrifugal forces in the rotating shell, is integrated into the model to reflect real-world conditions. The modified equations are then solved analytically to obtain the dispersion relations for the guided wave modes. The results reveal that the inclusion of GOP significantly alters the wave propagation characteristics, enhancing the shell’s ability to transmit high-frequency waves with minimal attenuation. The initial hoop tension is found to shift the frequencies of the guided wave modes, indicating a coupling effect between the mechanical loading and wave propagation. This study provides valuable insights into the dynamic behavior of reinforced concrete shells in high-speed rotational environments, offering a potential pathway for the design of advanced structural components in aerospace, automotive, and civil engineering applications.

Enhanced antimicrobial activity of photocatalytic titanium oxide upon formation of composites with polyaniline via an eco-friendly and facile microwave synthesis approach

This study proposes inexpensive antimicrobial polyaniline-titanium oxide (PANI-TiO2) samples prepared through eco-friendly enhanced microwave (MW) synthesis with 93 W applied over 10 min in aqueous 1.25 M hydrochloric acid media (HCl) using potassium iodate (KIO3) as oxidising agent, an approach suitable for industrial scale up production of PANI polymers at room temperature. The PANI-TiO2 samples are produced in the presence of 5–20 wt% of TiO2 in the initial reaction mixture along with aniline monomer by both the enhanced MW method and a classical chemical synthesis (CS) method at room temperature. The nanocomposites showed lower conductivity than pure PANI, slightly higher conductivity was observed in the MW prepared PANI-TiO2 in comparison to CS prepared PANI-TiO2. This result can be correlated with the observation that the optical absorbance of MW PANI-TiO2 samples were notable higher than for CS PANI-TiO2, which may be due to the presence of a greater amount of polarons present in the samples prepared by the enhanced MW method. MW PANI-TiO2 samples were equally active against both Gram-negative E. coli and Gram-positive S. aureus bacteria, in contrast to the CS PANI-TiO2 samples, which could be due to presence of short-chain fragments in the CS samples as confirmed by Fourier-transform infrared (FTIR) spectroscopy. The incorporation of PANI particles in TiO2 showed enhanced antimicrobial activity compared to pure TiO2, with greater antifungal activity. Our study indicates that a facile, low-cost, and green enhanced MW method can be used for preparation of the advanced antimicrobial PANI-TiO2 nanocomposites for biomedical applications.

Growth of nano-porous covalent organic frameworks on graphenic carbon hollow spheres; towards designing advanced multi-functional nanocomposites

For the first time, melamine-based covalent organic frameworks (COFs) were synthesized in situ on the graphenic shells of carbon hollow spheres (CHSs) for achieving a hybrid nanomaterial with unique thermo-mechanical characteristics. To improve the thermal stability of CHS-COF nanostructures (NSs), Zn2+/sodium L-glutamate (ZG) inorganic-organic complexes were loaded in their porosities and interior spaces (denoted as ZG@CHS-COF). The fabricated epoxy nanocomposites illustrated enhanced thermo-mechanical and UV-shielding properties. The tensile strength of the epoxy coatings, filled with CHS-COF and ZG@CHS-COF NSs, increased by 185 and 168 %, respectively, compared to the blank epoxy. DMTA results revealed that the glass transition temperature (Tg) of the epoxy, filled with CHS-COF and ZG@CHS-COF NSs increased around 2.1 and 8.1 °C, respectively. Also, the lower height of tan(δ) peaks (HTP) in the presence of CHS-COF and ZG@CHS-COF NSs illustrated their better interactions with epoxy chains. The highest ash content (≈46.3 %) and superior thermal durability were acquired in the presence of ZG@CHS-COF NSs. TEM results confirmed the better dispersion and distribution of ZG@CHS-COF NSs than CHS ones. The ZG@CHS-COF-filled epoxy coating led to a 71 % reduction in color changes (ΔE) after 3 weeks of UV irradiation.

On the dynamics of the elastic concrete systems reinforced by advanced nanocomposites

This work investigates the vibrational properties of doubly curved elastic concrete panels reinforced with multi-hybrid nanocomposites under in-plane loading. These cutting-edge materials use the advantages of several nanocomposites to produce greater performance by integrating many kinds of nanofibers and nanotubes to boost mechanical qualities. The study focuses on the effects of these reinforcements on the dynamic behavior of doubly curved panels, which are a typical structural component in contemporary engineering applications including civil infrastructure, automotive, and aerospace. The study investigates the natural frequencies and dynamic stability of the panels under in-plane stress circumstances using a thorough analytical method. The complicated geometry and material heterogeneity are modeled using mathematical modeling, which offers comprehensive insights into the impact of nanocomposite reinforcements. The findings show that, in comparison to conventional concrete panels, multi-hybrid nanocomposites considerably increase stiffness characteristics and vibrational performance. The results highlight the potential of these novel materials to transform structural component design and application, resulting in more robust and effective engineering solutions. By improving our knowledge of hybrid nanocomposite behavior under dynamic stresses, our study opens the door to a wider use of these materials science and engineering principles in materials science and engineering.

Preparation and characterization of transparent advanced smart nanocomposites reinforced by nanofibrillated cellulose/poly(methyl methacrylate)/methyl methacrylate/benzoyl peroxide

Transparent smart nanocomposites, which are among the advanced materials, were developed with the synergistic effect of nanofibrillated cellulose (NFCs) as a natural bionanomaterial, polymethyl methacrylate (PMMA) as a biocompatible microcapsule, methyl methacrylate (MMA) as a monomer, and benzoyl peroxide (BPO) as an initiator and catalyst. Epoxy resin was reinforced with NFC, PMMA, MMA, and BPO. Casting, which appears to be an industrially promising method that allows for cost-effective and high-quantity production, was used for producing transparent advanced nanocomposites. The properties of the nanocomposites, including yield strength, modulus of elasticity, hardness, impact energy, and self-healing capability, were determined. Increases in the yield strength (136.4%), modulus of elasticity (260%), hardness (28.3%), and impact energy (75%) were observed in the transparent smart nanocomposites reinforced with NFC, PMMA, MMA, and BPO, compared to pure epoxy composites. Furthermore, the transparent advanced smart nanocomposites self-healed by about 7% after the notch/scratch defect. It has the potential to be used in a variety of applications, such as interior and structural components for the aerospace and automotive industries, packaging, flexible screens, and lightweight transparent materials.

Introducing a computer simulation to model flexural vibrations of sandwich structures reinforced by advanced nanocomposites surrounded by auxetic concrete foundation

This study introduces a computer simulation framework aimed at analyzing the flexural vibrations of sandwich structures comprising a polymer core sandwiched between two face sheets reinforced with graphene oxide powder (GOP) nanocomposites. The sandwich structures are situated on an auxetic concrete foundation, incorporating sophisticated theoretical formulations to approximate the three-dimensional displacement fields of GOP-reinforced rectangular plates under varying loading conditions. The research addresses the complex interplay of material properties and geometric configurations, crucial for optimizing the structural performance of advanced composite materials in practical applications. The computational model integrates analytical techniques to predict the dynamic behavior of the sandwich structure’s flexural vibrations. Key parameters such as the dispersion of GOP within the polymer matrix, and the auxetic properties of the concrete foundation are systematically varied and analyzed to understand their impact on the overall structural response. Results from the simulations provide insights into the natural frequencies of the GOP-reinforced sandwich structures, offering valuable data for design engineers and materials scientists. The study underscores the potential of graphene oxide powder nanocomposites in enhancing the mechanical performance of sandwich structures, particularly when supported by innovative foundation materials like auxetic concrete. Future research directions include validation and further refinement of the computational model to accommodate additional complexities and real-world conditions.

Variation in wear scar penetration depths due to impact angle on the erosion wear of advanced aluminum matrix nanocomposites

In present study, developing (Al-Fe-Si) materials with high wear and erosion resistance for aerospace components, such as wing skin and fuselage sections, presents a significant challenge for researchers. This study delves into the reinforcement effects of TiC in aluminum composites, produced via ultrasonic-assisted stir casting. The focus lies on exploring the UASC technique to create composites with varied TiC weight percentages (0 %, 2 %, 4 %, and 6 % by weight) and evaluating their erosion resistance. Experiments varied erodent particle impact angle, velocity, and discharge rate, alongside impingement angles, and maintaining a constant velocity of 151 m/s for 10-minute durations, using solid particles averaging 201 µm in size. Increasing TiC content improved erosion resistance. Optical profilometry revealed a −131 µm maximum wear scar depth at a 45° impingement angle, with significantly higher erosion wear compared to other angles. These findings offer valuable insights for enhancing mechanical system design and durability. Eroded surface failure analysis utilized FE-SEM images to examine composites impacted by erodent forces.

In‐Situ Growth of MgO@rGO Core‐Shell Structure via CO2 Thermal Reaction for Enhanced Photocatalytic Performance

AbstractDegradation of organic pollutants in wastewater is crucial for global environmental health. Semiconductor‐based photocatalytic technologies have received widespread attention due to their ability to directly utilize solar energy, produce no secondary pollution, and offer long‐lasting functionality. However, current photocatalyst preparation technologies face issues such as complex manufacturing processes, low efficiency, and the need for various additives. Therefore, this work proposes a simple and eco‐friendly method to in‐situ growth of reduced graphene oxide (rGO) onto magnesium oxide (MgO), forming a MgO@rGO core‐shell structured photocatalyst through CO2 thermal reaction process. After systematic study, the incorporation of rGO onto MgO core greatly extends the light absorption range from ultraviolet (UV) to visible wavelength, enabling substantially enhanced light capture and photoexcited carriers. Additionally, the core‐shell heterojunction with a built‐in electric field at the interface between MgO and rGO facilitates distinctly the separation and migration of the photogenerated charges. This structure‐induced synergistic effect boosts the photocatalytic performance of MgO@rGO by a factor of 1.7, 4.1, 41.8, and 6.4, compared with MgO (stripped), MgO (pure), rGO, and commercially used TiO2, respectively. This work provides a simple and effective strategy for designing advanced functional nanocomposites to address environmental problems.

Introducing advanced nanocomposites to enhance the efficiency and stability of the car’s hood door subjected to axial loading via deep neural networks in the mathematical framework

In order to improve the efficiency and stability of automobile hood doors under axial loading circumstances, this research investigates the reinforcing of these doors using graphene oxide powders (GOP). This work is separated into two different parts. In the first part, using the mathematical modeling, the results of the presented applicable structure are obtained. After that using the datasets of the mathematical modeling section, the results of deep neural networks (DNN) are trained, tested, and validated. The work focuses on double-curved panels’ linear strain fields, which are an essential part of vehicle construction. We solve the governing equations and boundary conditions for the reinforced automobile hood doors by using Navier’s solutions. GOP greatly enhances the mechanical characteristics by offering better load-carrying capability and deformation resistance. Our results show that DNNs can reliably and effectively forecast the performance of GOP-reinforced structures, providing a useful tool for improving automobile hood door designs. Enhanced automobile safety and durability are made possible by the combination of cutting-edge computational methodologies and novel materials, which also meet the increasing need for high-performance car components. This work highlights the revolutionary power of both technologies on contemporary vehicle design and manufacture, underscoring the mutually beneficial relationship between nanomaterial reinforcement and machine learning in the advancement of automotive engineering.

Robust shape memory chlorobutyl rubber/boron nitride polymer nanocomposites for oil-water separation application

BackgroundBoron nitride (h-BN), an excellent 2D material finds exceptional applications in various fields owing to its unique characteristics including excellent hydrophobicity. Incorporation of boron nitride in polymer matrices is a captivating strategy by the scientific community to tune the properties of polymer. Interestingly, the possibilities of incorporating h-BN in chlorobutyl rubber (CIIR) matrix has never been considered and tried till now. Moreover, the use of CIIR to create a clean environment and reduce water pollution is an unexplored area even though the CIIR rubber possess excellent barrier properties. MethodsIn this work, two techniques were used for the fabrication of BNNS/CIIR nanocomposite. We exfoliated h-BN via chemical exfoliation method and tried the reinforcement of CIIR with BNNS via solution intercalation method. Shape memory analysis was performed with the help of stearic acid and oil-water separation analysis was achieved through an easy experimental technique. Significant findingsEnhanced mechanical strength of 11.57 MPa, improved thermal degradation temperature and char yield, higher glass transition temperature of -45.98° were observed for BNNS/CIIR nanocomposite reinforced with higher BNNS loading owing to the uniform distribution and better intercalation of BNNS in CIIR. Excellent shape memory was exhibited by CIIR matrix when reinforced up to 5 g BNNS. In addition, the nanocomposites displayed excellent ability to perform oil-water separation with increase in BNNS loading owing to the good hydrophobic character of h-BN and inherent barrier properties of CIIR. Thus, the study proved successful towards the fabrication of advanced CIIR nanocomposites with excellent shape memory and oil water separation efficiency.