Molybdenum tailings modified fly ash based geopolymers were an eco-friendly building material with excellent mechanical performance and fracture toughness. In this work, cubic compressive test and acoustic emission technique were used to evaluate the effect patterns of molybdenum tailings contents and thermal temperature conditions on the high-temperature mechanical performance and damage behaviors of molybdenum tailings modified fly ash-based geopolymers. The molybdenum tailings contents were 0 %, 10 %, 20 %, 30 % and 40 %, and the target temperatures were 300 °C, 600 °C and 900 °C, respectively. The results of compressive tests showed that the low contents of molybdenum tailings could limit the growth of macroscopic cracks during the loading process and improve the compressive strength of fly ash-based geopolymers when the heat treatment temperature did not exceed 600 °C. The acoustic emission results showed that 20 % molybdenum tailings contents could improve the structural stability and high-temperature mechanical performance of fly ash-based geopolymers, reduced the growth of microcracks in the specimen during the loading process, and delayed the formation and cracking of macrocracks, but did not change the specimen's compressive damage mode. The 40 % contents of molybdenum tailings changed the compressive damage mode of the fly ash-based geopolymers, delayed the cracking of the matrix structure under the peak loading, and significantly improved its resistance to plastic deformation.
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