Formation Of Acid Mine Drainage Research Articles

Sustainable Acid Mine Drainage Water Reclamation Using Silica-pectin Multichannel Tubular Membrane: A Comparison of Ultrafiltration Vs Pervaporation

The practice of coal mining has been demonstrated to exert a detrimental impact on the surrounding environment, particularly through the formation of acid mine drainage (AMD) ponds, which have the potential to pollute water sources. The reclamation of AMD is necessary to treat wastewater to ensure its safety for discharge into the environment and subsequent use as clean water. This study aims to treat AMD by comparing ultrafiltration (UF) and pervaporation (PV) processes utilizing silica-pectin multichannel membranes. The membranes were fabricated by coating silica-pectin sol on an inner surface of multichannel tubular support. The UF process was conducted under various pressures (1-3 bar), while the PV process was tested at various feed temperatures. Both permeate were collected and analyzed using several parameters (pH, Mn, and conductivity). The results showed that the UF process is more effective in collecting permeate flux over 136.6 L.h-1.m-2 at 3 bar pressure. Meanwhile, PV performs high permeate quality with Mn and conductivity rejection of 99.9 and 96.5%, respectively. Both UF and PV processes exhibit slightly increasing permeate pH with a range of 4.5-5.6. It concluded that multichannel silica-pectin membranes successfully reclamation AMD to enhance water quality. In addition, the UF process is more affordable for recycling AMD with high permeate flux, pretty good Mn, and conductivity rejection of over 95%.

Study of hydrophobic cemented paste backfill (H-CPB) to prevent sulphate attack

One of the challenges encountered in mining is acid mine drainage (AMD) in sulphurous ores in response to rainfall and groundwater. CPB one of the most prevalent waste management systems addresses this issue today. Nevertheless, in the long term, the concretion in CPB may become ineffective because of external factors, such as groundwater and rainfall. The relevant sources in the literature have no mention of AMD problems that may occur in the long term with CPB, particularly in metallic ores. Most studies indicate that the issue which can be prevented by using cement. However, due to the destructive effects of nature, cement alone would be insufficient. Consequently, the research's principal aim is to form CPB hydrophobic, thereby reducing the interaction between CPB and water. In the study, stearic acid was chosen as the hydrophobic agent and application method to the CPB and the changes in load-bearing capacity were studied. Specimens were tested by ion chromatography, X-ray diffraction (XRD), elemental analysis by combustion, water absorption, uniaxial compressive strength (UCS), and scanning electron microscopy (SEM). There was a decrease in the load-bearing capacity while gaining the hydrophobic properties of the material. The results confirm the validity of the selected agent and method and reveal that the effect of sulphate decreases with increasing hydrophobicity yet, there is no significant decrease in the 7, 14, and 28-day UCS tests. The optimal results were achieved when Stearic Acid (SA) was used at a concentration of 1.25 % for 7 % Portland cement and 0.75 % for 11 % Portland cement, with a UCS strength of 1.223 and 2.008 MPa, respectively. The expected benefit of stearic acid was realized as the water absorption value of the reference sample was 2.50 times higher in 7 % cement and 4.25 times higher in 11 % cement than the same value in Hydrophobic Cemented Paste Backfill (H-CPB). These results indicate that AMD formation can be prevented in the future with H-CPB. The results demonstrate that stearic acid, with the new methodology, forms the CPB hydrophobic, while only an acceptable strength loss was observed. Additionally, the outcomes point out that the methodology adopted does not consider a significantly adverse impact on hydration phase of concretation and can be utilized as an environmentally friendly backfilling method, thereby being evaluated as the cleaner backfilling for further CPB applications.

Improving the re-use potential of reactive waste rock using sieving: a laboratory geochemical study

Stockpiles containing sulfide minerals are subject to oxidation reactions when exposed to atmospheric conditions, which can result in the formation of acid mine drainage (AMD). Reactive waste rock has limited re-use potential due to the contamination risk associated with the generated drainage water. The re-use of reactive waste rock could lead to a significant reduction in the volume of waste rock as it mitigates the environmental impact of mine waste deposition. Acid mine drainage generation rate depends on sulfide weathering kinetics which are controlled by many parameters such as the mineralogy and the particle size. Fine fractions of waste rock have higher specific surface areas and degree of liberation of sulfides, resulting in greater reactivity than the coarse fractions. The objective of this research was therefore to evaluate the potential of re-use by controlling particle size using the sieving method. Two different potentially acid-generating waste rocks were divided into six fractions and subjected to both static and kinetic tests. Prediction of the geochemical behavior using static test did not consider the liberation of the minerals, and the long-term prediction was therefore overestimated. Results of the kinetic columns showed there was less oxidation of the sulfide minerals in the coarse fractions than in the fine fractions. Additionally, the distribution of sulfidic minerals and neutralizing minerals with particle size is influencing the potential of the re-use of the reactive waste rock.

Groundwater quality in high-sulfur coal mining region of India: Spatial distribution, source control, and health risk assessment

The groundwater quality in the vicinity of the Makum coalfield, renowned for its high-sulfur coal deposits, was investigated. The oxidation of sulfur in the coal generates acid mine drainage (AMD), a global environmental challenge that contaminates natural resources. The region's high sulfur coal content intensifies AMD formation, necessitating a comprehensive assessment of its impact on human health and the environment. This study analyzes the water quality parameters such as pH, EC, TDS, Na+, Ca+2, Mg+2, K+, HCO3‐, SO4−2, F−, Cl -, and NO3− in groundwater, findings concerning low pH levels (5.8) and fluoride concentration (0.15 mg/L) compared to standards. Groundwater chemistry was analyzed to identify the sources controlling water composition through Gibbs diagrams, Piper diagrams, and saturation indices. The Gibbs diagram shows that rock weathering is the crucial factor controlling groundwater chemistry, while the Piper diagram indicates Ca-Cl as the Principal water type. Additionally, an in-depth analysis of groundwater chemistry reveals that carbonate dissolution primarily occurs due to minerals like calcite, dolomite, and gypsum, findings supported by saturation indices. The present study yielded an average water quality index of 40.19, indicating excellent to good water quality in 51 out of 52 samples analyzed. The average hazard index values for adults and children were 0.60 and 0.58, respectively, indicating that 49 of 52 samples pose negative non-carcinogenic risks associated with nitrate and fluoride contamination. The irrigation indices, graphical representations such as the Wilcox and Doneen classification, and the USSL diagram elucidate the suitability for irrigation purposes. Moreover, the Principal Component Analysis identified the sources of ions as originating from geogenic processes and mining activities. The study stresses environmental assessments, health risk management, and sustainable practices for groundwater in high-sulfur coal mining areas.

Harnessing phosphate limestone waste as a cost-effective solution for acid mine drainage treatment

Mining mineral ores like pyrrhotite often generates positive and negative outcomes for the community. On the one hand these valuable minerals are explored to provide economic opportunities. On the other, mining pyrrhotite presents adverse environmental and health effects that relates to acid mine drainage (AMD) formation in abandoned mines. This suggest that the sustainable mining of valuable minerals in Pyrrhotite requires cost and environmentally friendly approaches. In this research, we simulate in-situ neutralisation effect of phosphate limestone waste (PLW) on AMD from two mining sites in Morocco under continuous oxic conditions. To this end, we conducted batch tests to assess the effectiveness of PLW in mitigating AMD and releasing contaminants. These tests involved reacting limestone particles (at two sizes: <2 cm and < 4 cm) with AMD leachates over a five-day period The results indicated that the AMD is characterised by a pH of 2.5 and an electrical conductivity of 11.8 mS/cm. The inductively coupled plasma optical emission spectroscopy (ICP-OES) analyses showed a high sulfate concentration of 3668.83 mg/L and the presence of some metals, notably copper, aluminium, and iron. The neutralisation process of the AMD using PLW under oxic conditions was highlighted by the variation in pH while the water was in contact with the PLW. The pH rose from 2.5 to 5.25 while the electrical conductivity decreased from 11.8 to 7.03 mS/cm. During the treatment of the AMD with PLW, the percentage of sulfate removal from the effluent was 35 %. In addition, iron and aluminium were significantly removed from the AMD with a percentage of 99 % in the leachate. Therefore, these results indicate that neutralising AMD using this passive treatment approach is effective and may serve as a cost-effective mitigation for AMD, since no excessive grinding is required for the PLW.

Microbial Mobilization and Reprecipitation of Transition Metals in Waste Rock from an Abandoned Pyrite Mine: Implications for Metal Recovery

Abstract The Pyrite Mines in Sulphide, Ontario are a collection of historic mine workings representing one of more than 6000 abandoned mines in Ontario. Historic mines are receiving renewed interest as potential sources of critical minerals for use in low carbon technologies. This study characterizes waste rock from the Pyrite Mines in the context of metal distribution, microbial activity, bioleaching, and acid mine drainage (AMD) bioremediation for the recovery of metals. Acidophilic Fe-oxidizing bacteria cultured from the waste rock produced schwertmannite [Fe8O8(OH)8−2x(SO4)x·nH2O] and ammoniojarosite [NH4Fe3(SO4)2(OH)6] with similar morphologies to those often observed in acidic sulfidic mine settings. Fe- and S-oxidizing bacteria found naturally in the waste rock were used in waste rock bioleaching column experiments that demonstrated AMD formation and metal mobilization. The columns produced acidic leachates (pH = 1.75) containing dissolved constituents, including sulfur (1577 mg/L), iron (547.7 mg/L), nickel (12.6 mg/L), manganese (7.3 mg/L), copper (2.3 mg/L), zinc (2.0 mg/L), chromium (1.5 mg/L), and titanium (0.7 mg/L). The proportion of metals successfully leached from the waste rock was variable, with leaching efficiencies calculated for nickel (31%), manganese (10.5%), iron (1.5%), chromium (1.4%), and titanium (0.02%). The leachates produced by the bioleaching columns were amended in subsequent bioremediation columns using sulfate reducing bacteria cultured from the mine site. Remediation efficiencies for elements of interest were calculated as cobalt (100%), chromium (100%), copper (100%), iron (90%), titanium (68%), nickel (52%), manganese (52%), and sulfur (43%). Mapping elemental distributions in thin sections from one of the bioleaching columns using synchrotron X-ray fluorescence microscopy revealed the heterogeneity of the waste rock. Iron was observed in both euhedral mineral grains, likely pyrite, and in secondary cements coating grains in the waste rock. Nickel, manganese, and chromium were primarily co-located with the iron. Titanium was primarily co-located with calcium in titanite (CaTiSiO5), making it challenging to target with bioleaching. This study demonstrates the heterogeneous nature of metal distribution in waste rock from this historic mine site. It indicates that successful metal recovery from legacy mine waste will require such materials to be treated as anthropogenic mineral deposits that require “exploration” and characterization much like naturally occurring ore deposits.

Legacy copper/nickel mine tailings potentially harbor novel iron/sulfur cycling microorganisms within highly variable communities.

The oxidation of sulfide-bearing mine tailings catalyzed by acidophilic iron and sulfur-oxidizing bacteria releases toxic metals and other contaminants into soil and groundwater as acid mine drainage. Understanding the environmental variables that control the community structure and metabolic activity of microbes indigenous to tailings (especially the abiotic stressors of low pH and high dissolved metal content) is crucial to developing sustainable bioremediation strategies. We determined the microbial community composition along two continuous vertical gradients of Cu/Ni mine tailings at each of two tailings impoundments near Sudbury, Ontario. 16S rRNA amplicon data showed high variability in community diversity and composition between locations, as well as at different depths within each location. A temporal comparison for one tailings location showed low fluctuation in microbial communities across 2 years. Differences in community composition correlated most strongly with pore-water pH, Eh, alkalinity, salinity, and the concentration of several dissolved metals (including iron, but not copper or nickel). The relative abundances of individual genera differed in their degrees of correlation with geochemical factors. Several abundant lineages present at these locations have not previously been associated with mine tailings environments, including novel species predicted to be involved in iron and sulfur cycling.IMPORTANCEMine tailings represent a significant threat to North American freshwater, with legacy tailings areas generating acid mine drainage (AMD) that contaminates rivers, lakes, and aquifers. Microbial activity accelerates AMD formation through oxidative metabolic processes but may also ameliorate acidic tailings by promoting secondary mineral precipitation and immobilizing dissolved metals. Tailings exhibit high geochemical variation within and between mine sites and may harbor many novel extremophiles adapted to high concentrations of toxic metals. Characterizing the unique microbiomes associated with tailing environments is key to identifying consortia that may be used as the foundation for innovative mine-waste bioremediation strategies. We provide an in-depth analysis of microbial diversity at four copper/nickel mine tailings impoundments, describe how communities (and individual lineages) differ based on geochemical gradients, predict organisms involved in AMD transformations, and identify taxonomically novel groups present that have not previously been observed in mine tailings.

A Comprehensive Review on Mine Tailings as a Raw Material in the Alkali Activation Process

The mining industry generates vast quantities of mine tailings on an annual basis. However, due to their limited economic value, a significant portion of these tailings are deposited close to mining sites, often underwater. The principal environmental apprehensions associated with mine tailings revolve around their elevated levels of heavy metals and sulfidic minerals. The oxidation of these sulfidic minerals can lead to the formation of acid mine drainage, which in turn releases heavy metals into nearby water systems. The effective management of tailing dams requires substantial financial investments for their construction and meticulous control. Consequently, a pressing need exists for stable, sustainable, and economically viable management approaches. One promising method for addressing mine tailings is through alkali activation, a technique that serves as a stabilization process. This approach yields robust, concrete-like structures by utilizing raw materials abundant in aluminum and silicon, which conveniently constitute the primary components of mining residues. This comprehensive review outlines the research on utilizing alkali activation for mine tailings. It delves into the reactivity and chemical attributes of diverse minerals. Numerous mine tailings exhibit an inadequate level of reactivity under alkaline conditions, so various pre-treatment methodologies and their impacts on mineralogy are meticulously explored.

A Fe(III)-driven strategy for efficient closed-loop recovery of critical metals from spent LiNixCoyMnzO2 powder

With the concepts of carbon peaking and carbon neutrality taking hold, the demand for recycling of spent lithium-ion batteries (LIBs) is increasing rapidly. However, current recycling methods are mostly faced with the dilemma of high cost and low efficiency and unable to meet the demand for energy conservation and consumption reduction. Here, inspired by the formation of acid mine drainage (AMD), we propose a Fe(III)-driven recovery approach, in which the leaching of valuable metals is enhanced by the addition of solid reagents Fe2(SO4)3 and pyrite (FeS2) to create an acidic reducing atmosphere. Under optimal conditions, the leaching efficiency of Ni/Co/Mn/Li reached 99.9%. In addition, NH3·H2O-NaOH was employed to adjust the pH of the leachate for stepwise precipitation of Fe and Ni/Co/Mn. Li was finally collected as Li2CO3 and Fe(III) could be recycled. We have also made attempts on Ni/Co/Mn co-precipitation and Li2CO3 resynthesis of regenerated LiNixCoyMnzO2 (NCM). It is predicted that this process can provide a green, efficient and economical closed-loop approach for cathode recovery of LIBs, with far-reaching implications for the entire battery recycling industry.

Treating waste with waste: Lignin acting as both an effective bactericide and passivator to prevent acid mine drainage formation at the source

Acid mine drainage (AMD) induced by pyrite oxidation is a notorious and serious environmental problem, but the management of AMD in an economical and environmentally friendly way remains challenging. Here, lignin, a natural polymer and abundant waste, was employed as both a bactericide and passivator to prevent AMD formation. The addition of lignin to a mimic AMD formation system inoculated with Acidithiobacillus ferrooxidans at a lignin-to-pyrite weight ratio of 2.5: 10 reduced the combined abiotic and biotic oxidation of pyrite by 68.4 % (based on released SO42−). Morphological characterization of Acidithiobacillus ferrooxidans revealed that lignin could act on the cell surface and impair the cell integrity, disrupting its normal growth and preventing biotic oxidation of pyrite accordingly. Moreover, lignin can be used alone as a passivator to form a coating on the pyrite surface, reducing abiotic oxidation by 71.7 % (based on released SO42−). Through multiple technique analysis, it was proposed that the functional groups on lignin may coordinate with iron ions on pyrite, promoting its deposition on the surface. In addition, the inherent antioxidant activity of lignin may also be actively involved in the abatement of pyrite oxidation via the reduction of iron. Overall, this study offered a “treating waste with waste” strategy for preventing AMD formation at the source and opened a new avenue for the management of AMD.

Inhibition of iron oxidation in Acidithiobacillus ferrooxidans by low-molecular-weight organic acids: Evaluation of performance and elucidation of mechanisms

The catalytic role of Acidithiobacillus ferrooxidans (A. ferrooxidans) in iron biooxidation is pivotal in the formation of Acid Mine Drainage (AMD), which poses a significant threat to the environment. To control AMD generation, treatments with low-molecular-weight organic acids are being studied, yet their exact mechanisms are unclear. In this study, AMD materials, organic acids, and molecular methods were employed to gain a deeper understanding of the inhibitory effects of low-molecular-weight organic acids on the biooxidation of iron by A. ferrooxidans. The inhibition experiments of A. ferrooxidans on the oxidation of Fe2+ showed that to attain a 90 % inhibition efficacy within 72 h, the minimum concentrations required for formic acid, acetic acid, propionic acid, and lactic acid are 0.5, 6, 4, and 10 mmol/L, respectively. Bacterial imaging illustrated the detrimental effects of these organic acids on the cell envelope structure. This includes severe damage to the outer membrane, particularly from formic and acetic acids, which also caused cell wall damage. Coupled with alterations in the types and quantities of protein, carbohydrate, and nucleic acid content in extracellular polymeric substances (EPS), indicate the mechanisms underlying these inhibitory treatments. Transcriptomic analysis revealed interference of these organic acids with crucial metabolic pathways, particularly those related to energy metabolism. These findings establish a comprehensive theoretical basis for understanding the inhibition of A. ferrooxidans' biooxidation by low-molecular-weight organic acids, offering a novel opportunity to effectively mitigate the generation of AMD at its source.

Peningkatan pH dengan Pemberian Bahan Organik pada Pengelolaan Air Asam Tambang Menggunakan Metode Passive Treatment

Mining is the process of extracting beneficial minerals from the surface of the earth that have an impact on the formation of acid mine drainage (AMD). One method of passive AMD management is passive treatment. This study used the Nested Factorial Experiment Design method. The types of organic matter used were empty fruit bunch oil palm (EFB) and cow dung, with doses of 0 Mg ha-1 (control), 50 Mg ha-1, 100 Mg ha-1, 150 Mg ha-1 and 200 Mg ha-1. Each treatment was three repeats so that 30 units of experimental units were obtained. The pH value of AMD in the untreated (control) reactor was 3.67. The initial reaction (pH) of AMD (0 days) with EFB application at a dose of 50 – 200 Mg ha-1 ranged from 3.63 – 4.28 and the initial pH of cow dung was 3.84 – 4.13. The reaction (pH) of the 1st to 4th weeks of AMD after adding EFB organic matter at a dose of 50 – 200 Mg ha-1 show a pH range (6.38 – 7.59) and cow manure at a dose of 150 – 200 Mg ha-1 show a pH (6.09 – 7.01). The conclusion are that the application of EFB organic matter on constructed wetland media for 4 weeks had a very real effect on increasing the pH of the AMD dose of 100 – 200 Mg ha-1 while cow dung 150 – 200 Mg ha-1 are the most effective against increasing pH.

Construction and application of a composite model for acid mine drainage quality evaluation based on analytic hierarchy process, factor analysis and fuzzy comprehensive evaluation: Guizhou Province, China, as a case.

The process of mining activities often causes the formation of acid mine drainage (AMD). Through rock fractures and underground rivers, AMD can easily enter the groundwater environment near mines and cause serious pollution to water quality. In order to effectively evaluate the quality of polluted mine water and to understand its threat to the ecosystem around the mine. In this study, four AMD pollution distribution areas, Guiyang City, Bijie City, Qianxinan Prefecture, and Qiandongnan Prefecture in Guizhou Province, were used as the study area. A composite model for mine water quality evaluation was constructed using factor analysis (FA), analytic hierarchy process (AHP), and fuzzy comprehensive evaluation (FCE). Furthermore, by introducing the weighted average method and the level characteristic value (J), the water quality type and the water body environmental quality were evaluated comprehensively, respectively. Compared with the traditional evaluation model, the AHP-FA-FCE model has obvious advantages in the selection of evaluation indicators, the determination of indicator weights, and the comprehensive evaluation of water quality types, and the evaluation results obtained are more reasonable and accurate. Three common factors mainly controlled by mineral oxidation factor, human activity factor, and mineral dissolution factor were extracted by dimension reduction of the original hydrochemical data by FA. The water quality of the mine water samples was evaluated using SO4 2- , Fe, Al, Mn, Na, and F- as evaluation indicators, and the results showed that the mine water samples in the study area as a whole were dominated by class V water, which accounted for 77.78% of the total. Based on the statistical analysis of the original data, it was found that influenced by the water-rock interactions in the study area and the AMD pollution components, the hydrochemical type of the mine water is mainly SO4 2- -Ca-Mg type. The water body environmental quality of mine water in four areas, Guiyang City, Qianxinan Prefecture, Bijie City, and Qiandongnan Prefecture, is from excellent to poor. The average level characteristic value of all the areas is more than 3, and the overall environmental quality of the water body is poor. The strong water-rock interaction and mining activities in the study area may be the main cause of AMD pollution. The results of this study may provide some theoretical reference for the water quality evaluation of AMD-polluted areas. PRACTITIONER POINTS: A composite model for mine water quality evaluation was constructed. A factor analysis-based evaluation indicator selection method is proposed. This study improved the weighting process of the traditional fuzzy comprehensive evaluation. A water quality discriminant based on the weighted average method is proposed. The water environmental quality of various types of mine water was evaluated.

Identifying sources of acid mine drainage and major hydrogeochemical processes in abandoned mine adits (Southeast Shaanxi, China).

Acid mine drainage (AMD) has resulted in significant risks to both human health and the environment of the Han River watershed. In this study, water and sediment samples from typical mine adits were selected to investigate the hydrogeochemical characteristics and assess the environmental impacts of AMD. The interactions between coexisting chemical factors, geochemical processes in the mine adit, and the causes of AMD formation are discussed based on statistical analysis, mineralogical analysis, and geochemical modeling. The results showed that the hydrochemical types of AMD consisted of SO4-Ca-Mg, SO4-Ca, and SO4-Mg, with low pH and extremely high concentrations of Fe and SO42-. The release behaviors of most heavy metals are controlled by the oxidation of sulfide minerals (mainly pyrite) and the dissolution/precipitation of secondary minerals. Along the AMD pathway in the adit, the species of Fe-hydroxy secondary minerals tend to initially increase and later decrease. The inverse model results indicated that (1) oxidative dissolution of sulfide minerals, (2) interconversion of Fe-hydroxy secondary minerals, (3) precipitation of gypsum, and (4) neutralization by calcite are the main geochemical reactions in the adit, and chlorite might be the major neutralizing mineral of AMD with calcite. Furthermore, there were two sources of AMD in abandoned mine adits: oxidation of pyrite within the adits and infiltration of AMD from the overlying waste rock dumps. The findings can provide deeper insight into hydrogeochemical processes and the formation of AMD contamination produced in abandoned mine adits under similar mining and hydrogeological conditions.

Microbiological and geochemical characterization of As-bearing tailings and underlying sediments

Over the past 100 years, extensive oxidation of As-bearing sulfide-rich tailings from the abandoned Long Lake Gold Mine (Canada) has resulted in the formation of acid mine drainage (pH 2.0–3.9) containing high concentrations of dissolved As (∼400 mg L−1), SO42-, Fe and other metals. Dissolved As is predominantly present as As(III), with increased As(V) near the tailings surface. Pore-gas O2 is depleted to < 1 vol% in the upper 30–80 cm of the tailings profile. The primary sulfides, pyrite and arsenopyrite, are highly oxidized in the upper portions of the tailings. Elevated proportions of sulfide-oxidizing prokaryotes are present in this zone (mean 32.3% of total reads). The tailings are underlain by sediments rich in organic C. Enrichment in δ34S-SO4 in pore-water samples in the organic C-rich zone is consistent with dissimilatory sulfate reduction. Synchrotron-based spectroscopy indicates an abundance of ferric arsenate phases near the impoundment surface and the presence of secondary arsenic sulfides in the organic-C beneath the tailings. The persistence of elevated As concentrations beneath the tailings indicates precipitation of secondary As sulfides is not sufficient to completely remove dissolved As. The oxidation of sulfides and release of As is expected to continue for decades. The findings will inform future remediation efforts and provide a foundation for the long-term monitoring of the effectiveness of the remediation program.

Comparative study of long-term laboratory and field kinetic test for potential acid forming (PAF) materials

Acid Mine Drainage (AMD) comes from open pit and underground mining activities, characterized by high level of acidity and high metal solubility. AMD is formed from sulfide minerals that are exposed from mining activities, undergo oxidation by oxygen and contact with rainwater. AMD formation reaction rate must be studied to prevent AMD from being released to the environment. Reaction rate of acid formation can be determined by kinetic test. This study used the Free Draining Column Leach (FDCL) test method for the kinetic test, performed in laboratory scale and field scale. Laboratory scale experiment was done in a cylinder reactor, with 15 cm diameter and 35 cm height. Meanwhile the field scale was carried out in greater amount of rock material and reactor volume. The test was carried out in a weekly cycle for a total of 83 weeks. This study states that field scale experiments tend to produce higher concentrations of ORP, conductivity, sulfate, iron (Fe) and manganese (Mn) rather than the laboratory scale. The pH parameter on field scale experiment is around 1.91 to 3.18, meanwhile on the laboratory scale experiment is around 2.18 to 3.47. It can be interpreted that the field scale experiment tends to produce more acidic pH compared to the laboratory scale experiment. This research is expected to find the differences between laboratory scale and field scale experiments in long-term kinetic tests.

Old Sulfidic Ore Tailing Dump: Ground Features, Mineralogy, Biodiversity—A Case Study from Sibay, Russia

The Urals (Russia) are among the largest mining areas in the world, with millions of tons of mine waste deposited. An old sulfidic tailing dump formed over decades of mining activities at the Sibay ore-processing plant is a typical cause of acid mine drainage (AMD) formation, posing a threat to ecosystems of neighboring environments. In this study, the formation of oxidized surface soil layers in four zones of the Sibay tailing dump was revealed, and their chemical–mineralogical and physical–mechanical characteristics were analyzed. According to the results of the metabarcoding of hypervariable regions of the 16S rRNA genes, oxidation in soil layers was associated with the activity of sulfur- and iron-oxidizing acidophiles represented by a few genera: Ferroacidibacillus, Sulfoacidibacillus, Sulfobacillus, and Ferroplasma. The structure of the microbial communities in soil layers differed depending on the zone and depth of sampling. In the samples characterized by the weak oxidation of sulfide minerals, microbial communities were dominated by bacteria of the genus Pseudomonas. The data obtained in this research are of importance to predict the oxidation/leaching processes in mine wastes and their negative environmental impacts in the mining region, as well as to develop technologies for processing these raw materials.

The Effects of Cobalt Mining on Water Quality and the Dispersion of Contaminants in the Environment

Cobalt mining, essential for various technological advancements including battery production and electronics, has raised significant environmental concerns due to its potential impact on water quality and the release of contaminants into the surrounding ecosystems. This study aims to assess the repercussions of cobalt mining activities on water bodies and the fate of associated contaminants within the environment.Through a comprehensive literature review and field investigations, this research examines the mechanisms by which cobalt extraction processes, including open-pit mining and leaching techniques, contribute to water contamination. The study evaluates the release of heavy metals such as cobalt, nickel, copper, and arsenic, along with the formation of acid mine drainage (AMD), resulting from sulfide mineral exposure during mining operations. Furthermore, this investigation delves into the persistence and behavior of contaminants released during cobalt mining. It explores the long-term implications of heavy metal accumulation in sediments, soils, and biota, emphasizing the potential for biomagnification and ecological disruption within aquatic ecosystems.Human health concerns related to waterborne contaminants originating from cobalt mining activities are also addressed in this study, highlighting the risks associated with the consumption of contaminated water by local communities.The research findings underscore the necessity for robust environmental regulations, sustainable mining practices, effective waste management strategies, and remediation efforts to mitigate the adverse impacts of cobalt mining on water quality and environmental health. Furthermore, the study emphasizes the importance of continued monitoring and research to better understand the full extent of the problem and develop targeted solutions to safeguard water resources and ecosystems affected by cobalt mining. Keywords: Cobalt mining, Water contamination, Heavy metals, Acid mine drainage (AMD), Environmental impacts, Water quality degradation, Contaminants in mining, Aquatic ecosystems

Analysis of Acid Mine Drainage Formation Potential on Coal Stratification in Lamuru Area, Bone Regency, South Sulawesi Province

The open-pit mining system in coal mines causes the rocks at the mining site to be exposed to the surface so that water and air will react with rocks directly which will cause the formation of acid mine drainage, diverse morphological coditions with many springs and agricultural fields around the research area have an important role that must be maintained so as not to be polluted or damage agricultural land. The purpose of this study was to analyze the presence of sulfide minerals with sulfur content in coal stratification as the initial potential of acid mine drainage, in the lithology of the study area obtained seven lithological samples on coal stratification including overburden, S-01 (siltstone), S-02 (coal seam 1), S-03 (siltstone), S-04 (claystone), S-05 (coal seam 2), S-06 (sandstone) and S-07 (top soil). The results of the X-ray Diffraction (XRD) analysis detected the presence of pyrite minerals, with the results of the analysis of total sulfur ranging from 0.046 to 4.62%, and the results of the analysis of scanning electron microscope (SEM) obtained anhedral, subhedral and framboidal morphology This type of framboidal pyrite is a very fine crystal, very fast to react with air so that this pyrite is believed to be a trigger for the formation of acid mine drainage.

Impact of roots on the hydrogeological properties of silty soil covers

Mine tailings storage poses significant environmental risks such as the formation of acid mine drainage. Engineered covers offer a solution by controlling water ingress. Their performance is based on specific soil hydrogeological properties (SHPs). They must support vegetation which can impact saturated hydraulic conductivity ( ksat) and water retention curve (WRC). This study assesses the impact of 4-year-old willow root colonization on silty soil covers using flexible wall parameters and water retention tests. The obtained SHPs were compared with root traits. The results suggested that the hydrogeological properties of the studied in situ samples were not significantly affected by roots. The variation of measured and predicted ksat values spanned an order of magnitude, regardless of the root colonization intensity, up to a root length density (RLD) of 2.98 cm/cm3. RLD showed a significant and positive linear relationship with measured ksat values ( R2 = 0.54). However, when root colonization was low (RLD &lt; 1 cm/cm3), RLD was negatively correlated with the nvG ( R2 = 0.44) parameter of the van Genuchten WRC model, while the opposite relationship was observed for samples with RLD &gt; 1 cm/cm3 ( R2 = 0.61). Additionally, RLD and the coarse root (diameter &gt; 1 mm) volume to fine root volume (C/F ratio) influenced WRCs. Over time, coarser roots may have a more pronounced impact on SHPs; further research is needed.