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Electrochemical double layer capacitors with PEO and Sri Lankan natural graphite

Electrochemical double layer capacitors (EDLCs) have received a tremendous interest due to their suitability for diverse applications. They have been fabricated using different carbon based electrodes including activated carbons, single walled/multi walled carbon nano tubes. But, graphite which is one of the natural resources in Sri Lanka has not been given a considerable attention towards using for EDLCs though it is a famous carbon material. On the other hand, EDLCs are well reported with various liquid electrolytes which are associated with numerous drawbacks. Gel polymer electrolytes (GPE) are well known alternative for liquid electrolytes. In this paper, it is reported about an EDLC fabricated with a nano composite polyethylene oxide based GPE and two Sri Lankan graphite based electrodes. The composition of the GPE was [{(10PEO: NaClO4) molar ratio}: 75wt.% PC] : 5 wt.% TiO2. GPE was prepared using the solvent casting method. Two graphite electrodes were prepared by mixing 85% graphite and 15% polyvinylidenefluoride (PVdF) in acetone and casting n fluorine doped tin oxide glass plates. GPE film was sandwiched in between the two graphite electrodes. A non faradaic charge discharge mechanism was observed from the Cyclic Voltammetry study. GPE was stable in the potential windows from (-0.8 V-0.8 V) to (-1.5 V-1.5 V). By increasing the width of the potential window, single electrode specific capacity increased. Impedance plots confirmed the capacitive behavior at low frequency region. Galvanostatic charge discharge test yielded an average discharge capacity of 0.60 Fg-1.

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Sensitivity analysis of numerical schemes in natural cooling flows for low power research reactors

The advantages of using natural circulation (NC) as a cooling system, has prompted the worldwide development to investigate this phenomenon more than before. The interesting application of the NC in low power experimental facilities and research reactors, highlights the obligation of study in these laminar flows. The inherent oscillations of NC between hot source and cold sink in low Grashof numbers necessitates stability analysis of cooling flow with experimental or numerical schemes. For this type of analysis, numerical methods could be implemented to desired mass, momentum and energy equations as an efficient instrument for predicting the behavior of the flow field. In this work, using the explicit, implicit and Crank-Nicolson methods, the fluid flow parameters in a natural circulation experimental test loop are obtained and the sensitivity of solving approaches are discussed. In this way, at first, the steady state and transient results from explicit are obtained and compared with experimental data. The implicit and crank-Nicolson scheme is investigated in next steps and in subsequent this research is focused on the numerical aspects of instability prediction for these schemes. In the following, the assessment of the flow behavior with coarse and fine mesh sizes and time-steps has been reported and the numerical schemes convergence are compared. For more detail research, the natural circulation of fluid was modeled by ANSYS-CFX software and results for the experimental loop are shown. Finally, the stability map for rectangular closed loop was obtained with employing the Nyquist criterion.

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Prioritizing the locations for hydrogen production using a hybrid wind-solar system: A case study

Energy is a major component of almost all economic, production, and service activities, and rapid population growth, urbanization and industrialization have led to ever growing demand for energy. Limited energy resources and increasingly evident environmental effects of fossil fuel consumption has led to a growing awareness about the importance of further use of renewable energy sources in the countries energy portfolio. Renewable hydrogen production is a convenient method for storage of unstable renewable energy sources such as wind and solar energy for use in other place or time. In this study, suitability of 25 cities located in Iran\'s western region for renewable hydrogen production are evaluated by multi-criteria decision making techniques including TOPSIS, VIKOR, ELECTRE, SAW, Fuzzy TOPSIS, and also hybrid ranking techniques. The choice of suitable location for the centralized renewable hydrogen production is associated with various technical, economic, social, geographic, and political criteria. This paper describes the criteria affecting the hydrogen production potential in the study region. Determined criteria are weighted with Shannon entropy method, and Angstrom model and wind power model are used to estimate respectively the solar and wind energy production potential in each city and each month. Assuming the use of proton exchange membrane electrolyzer for hydrogen production, the renewable hydrogen production potential of each city is then estimated based on the obtained wind and solar energy generation potentials. The rankings obtained with MCDMs show that Kermanshah is the best option for renewable hydrogen production, and evaluation of renewable hydrogen production capacities show that Gilangharb has the highest capacity among the studied cities.

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Metal effects in Mn-Na<sub>2</sub>WO<sub>4</sub>/SiO<sub>2</sub> upon the conversion of methane to higher hydrocarbons

The roles of Na, Mn, W and silica, and the synergistic effects between each metal in the <TEX>$MnNa_2WO_4/SiO_2$</TEX> catalyst have been investigated for oxidative coupling of methane (OCM). The crystallisation of amorphous silica during calcination at <TEX>$900^{\circ}C$</TEX> was promoted primarily by Na, but Mn and W also facilitated this process. The interaction between Na and Mn tended to increase the extent of conversion of <TEX>$Mn_3O_4$</TEX> to <TEX>$Mn_2O_3$</TEX>. The formation of <TEX>$Na_2WO_4$</TEX> was dependent on the order in which Na and W were introduced to the catalyst. The impregnation of W before Na resulted in the formation of <TEX>$Na_2WO_4$</TEX>, but this did not occur when the impregnation order was reversed. <TEX>$MnWO_4$</TEX> formed in all cases where Mn and W were introduced into the silica support, regardless of the impregnation order; however, the formation of <TEX>$MnWO_4$</TEX> was inhibited in the presence of Na. Of the prepared samples in which a single metal oxide was introduced to silica, only <TEX>$Mn/SiO_2$</TEX> showed OCM activity with significant oxygen conversion, thus demonstrating the important role that Mn plays in promoting oxygen transfer in the reaction. The impregnation order of W and Na is critical for catalyst performance. The active site, which involves a combination of Na-Si-W-O, can be formed in situ when distorted <TEX>$WO_4^{2-}$</TEX> interacts with silica during the crystallisation process facilitated by Na. This can only occur if the impregnation of W occurs before Na addition, or if the two components are introduced simultaneously.

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Evaluation of thermal comfort and cooling loads for a multistory building

The latest UK Climate Projections (UKCP09) show that mean daily temperatures will increase everywhere in the United Kingdom. This will significantly affect the thermal and energy performance of the current building stock. This study examines an institutional fully glazed building and looks into the changes in the cooling loads and thermal comfort of the occupants during the occupied hours of the non-heating period. Furthermore, it investigates the effect of relative humidity (RH) on thermal comfort. The Design Summer Year (DSY) 2003 for London Heathrow has been used as a baseline for this study and the DSY 2050s High Emissions scenario was used to examine the performance of the building under future weather conditions. Results show a 21% increase of the cooling loads between the two examined scenarios. Thermal comfort appears to be slightly improved during the months of May and September and marginally worsen during the summer months. Results of the simulation show that a relative humidity control at 40% can improve the thermal comfort for 53% of the occupied hours. A comparison of the thermal comfort performance during the hottest week of the year, shows that when the relative humidity control is applied thermal comfort performance of the 2050s is similar or better compared to the thermal comfort performance under the baseline.

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