Volcanic ashes (VA) ejected by the Tajogaite Volcano were studied to determine their potential as pozzolanic materials for construction applications. A representative number of VA samples (15 in total) were collected from different geolocations and altitudes during and immediately after the volcanic eruption, in order to assess their reactivity as a function of position and environmental exposure. Various analytical techniques—XRD, FTIR, and SEM/EDX—were used to determine the initial microstructural composition of the VA samples. Additionally, saturated lime testing and the Frattini test were performed to evaluate their pozzolanic reactivity for use in historical mortars. The microstructural analyses revealed that the dominant mineral phases are aluminosilicates. The reactivity tests confirmed a good pozzolanic response, with the formation of C-A-S-H gels identified as the main hydration products at the studied curing times.

A primary challenge in the further development of anion sensors in real water samples of environmental concern is the need for highly water-soluble compounds that are able to detect low concentrations of analytes. Small-molecule sensors can mitigate solubility constraints and highly aromatic or conjugated systems may provide a new way to recognize target analytes with high sensitivity and/or selectivity. Organic aggregates that have the ability to form large frameworks can exhibit aggregated-induced emissions to detect target analytes, and their coagulation can provide enhanced detection via colorimetric or fluorescent measurements. This review aims to draw attention to the emerging area of small-molecule organic chemosensors that utilize aggregation to detect environmentally detrimental anions in an aqueous solution. A number of mechanisms of interaction for anion recognition are recognized and discussed here, including electrostatic interactions, covalent bond formation, hydrophobic interactions, and even complexation.

The chemical industry faces major challenges worldwide. Since 1950, production has increased 50-fold and is projected to continue growing, particularly in Asia. It is one of the most energy- and resource-intensive industries, contributing significantly to greenhouse gas emissions and the depletion of finite resources. This development exceeds planetary boundaries and calls for a sustainable transformation of the industry. The key transformation areas are as follows: (1) Non-Fossil Energy Supply: The industry must transition away from fossil fuels. Renewable electricity can replace natural gas, while green hydrogen can be used for high-temperature processes. (2) Circularity: Chemical production remains largely linear, with most products ending up as waste. Sustainable product design and improved recycling processes are crucial. (3) Non-Fossil Feedstock: To achieve greenhouse gas neutrality, oil, gas, and coal must be replaced by recycling plastics, renewable biomaterials, or CO2-based processes. (4) Sustainable Chemical Production: Energy and resource savings can be achieved through advancements like catalysis, biotechnology, microreactors, and new separation techniques. (5) Sustainable Chemical Products: Chemicals should be designed to be “Safe and Sustainable by Design” (SSbD), meaning they should not have hazardous properties unless essential to their function. (6) Sufficiency: Beyond efficiency and circularity, reducing overall material flows is essential to stay within planetary boundaries. This shift requires political, economic, and societal efforts. Achieving greenhouse gas neutrality in Europe by 2050 demands swift and decisive action from industry, governments, and society. The speed of transformation is currently too slow to reach this goal. Science can drive innovation, but international agreements are necessary to establish a binding framework for action.

This work reviews the use of biodiesel synthesis experiments in science education, emphasising their potential for explicit nature of science (NOS) teaching. Through a literature review and experimental insights, it highlights how transesterification of waste cooking oil (WCO) with a basic catalyst can serve as an educational tool. While biodiesel reaction conditions are well-documented, this study presents them in a pedagogical context. Simple viscosity and density measurements illustrate empirical analysis, while a design of experiments (DoE) approach using a Hadamard matrix introduces systematic optimisation and scientific reasoning. By integrating biodiesel synthesis with explicit NOS instruction, this work provides educators with a framework to foster critical thinking and a deeper understanding of scientific inquiry. Additionally, this approach aligns with green chemistry principles and resource efficiency, reinforcing the broader relevance of sustainable chemistry.

Rambutan peel is a great source of bioactive compounds, the same that, over the years, has been extracted using conventional technologies which have been proven to be harmful to the environment and potentially toxic to human beings. This study aimed to extract the same compounds using a hybridization of ultrasound/microwave extraction. The results were promising, as a total of 378.48 ± 9.19 mg/g of polyphenols were recovered from this procedure, and the most important molecules (geraniin, corilagin, and ellagic acid) were identified, giving this much more relevance. Furthermore, treatment with rambutan peel extract recovered with green technologies significantly reduced cell viability in HCV-infected liver cells. Notably, higher concentrations (4000 and 5000 ppm) led to more pronounced cell death in huh7 cells. The treatment also led to a significant reduction in viral protein and RNA expression in HCV-infected cells. These findings suggest that rambutan peel extract obtained from the combination of ultrasound and microwave extraction, particularly the ellagitannins present, have potential antiviral properties. Further research is needed to explore its mechanism of action and its potential as a therapeutic agent for Hepatitis C.

Physical pretreatments play a crucial role in reducing the recalcitrance of lignocellulosic biomass, facilitating its conversion into fermentable sugars for bioenergy and chemical applications. This study critically reviews physical pretreatment approaches, including mechanical comminution, irradiation (ultrasound, microwave, gamma rays, and electron beam), extrusion, and pulsed electric field. The discussion covers the mechanisms of action, operational parameters, energy efficiency, scalability challenges, and associated costs. Methods such as ultrasound and microwave induce structural changes that enhance enzymatic accessibility, while extrusion combines thermal and mechanical forces to optimize hydrolysis. Mechanical comminution is most effective during short periods and when combined with other techniques to overcome limitations such as high energy consumption. Innovative approaches, such as pulsed electric fields, show significant potential but face challenges in large-scale implementation. This study provides technical and strategic insights into developing more effective physical pretreatments aligned with economic feasibility and industrial sustainability.

Sustainable hydrocarbons are one of the main methods of decreasing the use of fossil fuels and derivatives, contributing to the mitigation of environmental impacts and greenhouse gas emissions. Circular economic concepts focus on reusing waste by converting it into new products, which are then input again into industrial production lines, thus decreasing the necessity of fossils. Polypropylene-based plastic waste can be depolymerized into smaller chemical chains, producing a liquid phase rich in hydrocarbons. In the same way, triacylglycerol-based waste biomasses can also be converted into renewable hydrocarbons. Our research studied the co-processing of polypropylene (PP) and cottonseed oil dreg (BASOs) waste from the biodiesel industry using a micropyrolysis system at 550 °C, previously validated to predict the scale-up of the process. PP showed the production of alkanes and alkenes, while BASOs also produced carboxylic acids in addition to the PP products. The main impacts were observed in the conversion yields, reaching the highest values of pyrolytic liquid (64%), gas (14%), and solid product (13%) compared to the co-processing mixture of BASO:PP (1:2). Also, in this mixture, the production of carboxylic acids decreased to the lowest value (~10%), improving the conversion to sustainable hydrocarbons.

Chlorella sp. was cultivated in a closed system using PET bottles (5 L) and with the continuous injection of air and commercial gas (98% CO2) and in simulated conditions (15% CO2, 73% N2, and 12% O2). The culture medium was prepared using well water and mining wastewater, the cultivation period occurred in a 10-day cycle, and the cell growth curves were evaluated through cell counting using a Neubauer chamber. The cultivation was carried out under the following conditions: temperature at 22 °C to 25 °C; aeration rate with commercial and simulated CO2 gas at 0.01 vvm; and synthetic air containing 0.042% CO2. The dry biomass productivity was 0.81 g·L−1·day−1 and the maximum CO2 fixation rate was 0.90 g·L−1·day−1 when the microalgae were cultivated with a continuous flow of simulated waste gas and a culture medium composed of wastewater. The percentages of macromolecules obtained in the biomass cultivated in wastewater reached 20.95%, 26.48%, and 9.3% for lipids, proteins, and carbohydrates, respectively.

Twelve marine-derived fungal strains were evaluated for their ability to synthesize silver nanoparticles (AgNPs). Mycogenic AgNPs were preliminarily characterized using different techniques, and their antimicrobial activities were assessed. Penicillium citrinum IBCLP11 and Aspergillus niger IBCLP20 were selected for AgNPs’ synthesis optimization by varying parameters such as AgNO3 concentration, biomass, agitation, temperature, and pH. AgNPIBCLP11 and AgNPIBCLP20 were able to inhibit the growth of Pseudomonas aeruginosa IPT322, Staphylococcus aureus IPT246, and Klebsiella pneumoniae IPT412 at concentrations of 25 μg/mL or higher. Aspergillus niger IPT295 and Aspergillus parasiticus IPT729 were the most sensitive to AgNPIBCLP20. Further studies are needed to fully elucidate the effects of all parameters influencing mycogenic AgNPs synthesis. However, it is evident that maintaining optimal conditions, such as temperature and pH during agitation, is crucial for preventing undesirable reactions and ensuring nanoparticle stability.

Zeolites are amongst the most extensively explored crystalline microporous materials because of their variable chemical composition, framework geometry, pore dimensions, and tunability. Due to their high surface area, adsorption selectivity, mechanical, biological, chemical, and thermal stability, these molecular sieves are widely used in adsorption, catalysis, ion exchange, and separation technologies. This short review highlights the notable progress achieved in leveraging the properties of zeolite materials for multiple applications, including gas separation and storage, adsorption, catalysis, chemical sensing, and biomedical applications. The aim is to emphasize their capabilities by showcasing important achievements that have driven research in this field toward new and unforeseen areas of material chemistry.