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ATOMIZATION AND MIXING OF BLENDED ENERGETIC IONIC LIQUID HYDROXYETHYLHYDRAZINIUM NITRATE

Hypergolic propellants are widely used in liquid rocket propulsion. Instantaneous control of combustion, lack of requirement of an ignition system, and storability for long durations are the major advantages of hypergolic propellants. The propellant community is on the lookout for replacements for the currently utilized toxic hydrazine and its derivatives. Energetic hypergolic ionic liquids are excellent candidates for such replacement. However, their high viscosity and surface tension render atomization difficult, and hence, increase the ignition delays in the combustion chamber and reduce combustion efficiency. The current study focuses on the geometrical aspects of injector design and other injection conditions that control the ignition process and combustion efficiency. These mainly depend on the extent of mixing and atomization. Shadowgraphy and patternator-based experiments were performed on doublet and triplet impingement injectors under variable injection conditions, such as impingement angle, jet diameters, and injection velocities. A blend of 50% unsymmetrical dimethylhydrazine in the energetic ionic liquid hydroxyethylhydrazinium nitrate (UHN50) shows promise as a candidate for a hydrazine replacement. A blend of 38% ethanol in glycerol (GE6238) was used as a surrogate for UHN50, whereas water was used as a surrogate for nitrogen tetroxide. The effect of variation of injection conditions was found to be contradictory for achieving atomization and mixing. An optimum criterion was obtained for both atomization and mixing.

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EXPERIMENTAL INVESTIGATION OF UNLIKE TRIPLET SPRAYS USING HIGH-MAGNIFICATION SHADOWGRAPHY: INFLUENCE OF THE JETS VELOCITIES AND CENTRAL JET PROPERTIES

In this study, inert liquid sprays are generated by impinging two symmetric jets of water with a central jet of water, ethanol, or n-dodecane. This configuration, referred to as an unlike triplet injector, can be used in rocket engines to atomize liquid storable propellants, for instance, hydrogen peroxide oxidizer combined to a fuel. Here, the inert sprays are investigated in the so-called impact waves regime, which corresponds to jets a Weber number of higher than 1000. The atomization process is characterized using high-magnification shadowgraphy (HMS) from the impinging point of the jets into a sheet until it breaks up into ligaments and droplets. The HMS technique enables 10 kHz visualizations with an interframe of 4 μs and a spatial resolution up to 6.4 μm/pixel (1024 × 1024 pixels). Characteristic lengths of the primary atomization are measured: breakup length, apparent wavelength, and ligaments size. Similarly, the droplet populations are described based on arithmetic and Sauter mean diameters, shape, and velocity. Statistics of large droplet distributions are analyzed regarding the injection conditions and distance to the impingement point. Compared to like-doublet spray, the like-triplet evidences a slower atomization (longer breakup distance) and generates larger drops that require more distance to stabilize in size, centricity, and velocity. Unlike-triplet sprays exhibit a similar behavior to like-triplet spray while producing larger droplets, probably because of the fuel properties that stabilize the liquid sheet.

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NUMERICAL STUDY OF DIRECT INJECTION SPRAY BEHAVIOR OF GASOLINE AND METHANOL-GASOLINE BLENDS UNDER SPLIT-INJECTION STRATEGY IN ENGINE-LIKE CONDITIONS

Several studies have shown that the split-injection strategy has improved the shortcomings of the high particulate matter emissions and cycle-to-cycle variations in homogeneous and stratified combustion modes of gasoline direct injection (GDI) engines. However, the spray behavior under the split injection strategy is poorly understood. This study uses computational fluid dynamics (CFD) simulations in Converge software to investigate the spray characteristics of gasoline and methanol-gasoline blends under a split-injection strategy. The simulation studies were performed for a multihole GDI injector in a constant volume spray chamber, replicating the ambient conditions similar to a GDI engine's homogeneous and stratified combustion modes. Appropriate models for simulating different spray phenomena, such as spray breakup, collision, and coalescence, were used. The CFD model was validated using the experimental spray penetration length provided in the engine combustion network database. The results showed that the split-injection reduced the Sauter mean diameter (SMD) of fuel spray droplets and liquid fuel mass content than a single injection case. The dwell time of 2 ms was found suitable for homogeneous mode conditions, while its effect was insignificant in stratified mode conditions. Further, a split ratio of 80:20 resulted in smaller SMD during the injection period and a higher fuel evaporation rate. The effect of methanol addition was also explored under the split-injection mode. M85 showed higher deviations in the liquid spray penetration, SMD, and liquid spray mass content than G100.

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DOPPLER OPTICAL PROBE FOR DROP SIZE, VELOCITY, AND FLUX MEASUREMENTS IN ASSISTED ATOMIZATION

For research as well as for process control, reliable drop size, velocity, and flux measurements are desirable in particular in dense, high-speed flows. A new optical probe has been recently manufactured by A2 Photonic Sensors company that combines an accurate phase detection capability (its latency length is small, about 6 µm) with the collection of a Doppler signal that provides the absolute velocity of an incoming gas-liquid interface. In this article, raw signals acquired over diverse flow conditions in terms of gas velocity and liquid concentration are analyzed. A dedicated signal processing routine is then proposed and optimized. The latter provides statistics on drop velocity and size. It also gives access to local liquid concentration and liquid flux. This Doppler probe combined with its processing has been tested in sprays produced from assisted atomization over a wide range of flow conditions. Transverse profiles of spray characteristics are presented for gas injection velocities ranging from 32 m/s to 283 m/s, for drops Sauter mean diameters D<sub>32</sub> varying from 37 µm to 275 µm, and for number densities-as estimated from liquid concentration and D<sub>32</sub>-comprised between 1 #/mm<sup>3</sup> and 218 #/mm<sup>3</sup>. The Doppler probe happens to be able to consistently detect chords as small as 4 µm, and to ensure a significant (up to 70%) fraction of direct velocity measurements. Besides, the injected liquid flow rate is recovered from the spatial integration of local liquid fluxes within 8% for gas velocities up to 50 m/s and within 17% for gas velocities above 90 m/s. Hence, the new Doppler probe combined with the proposed processing provides reliable statistics on drop velocity, size, and flux, and is a valuable tool for investigating dense, high-velocity, and fine sprays.

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MACROSCOPIC SPRAY CHARACTERISTICS OF GASOLINE, METHANOL, AND ETHANOL IN DIRECT INJECTION SPARK IGNITION ENGINE-LIKE CONDITIONS

In recent decades, stringent emission norms have been enforced upon the engine research community and OEMs to encourage them to develop new spark ignition engine technologies, such as variable valve lifts, turbocharging, and direct injection spark ignition (DISI) engines. For further development, greater control of parameters such as in-cylinder air motion, spray characteristics, injection, and ignition events is required. Spray characterizations are crucial for understanding the mixing phenomena in heated and pressurized engine combustion chamber conditions. Spray pattern, fuel injection pressure (FIP), rate shape, and thermodynamic conditions of the combustion chamber play a vital role in the mixture preparation. The present study uses Mie-Scattering techniques to examine spray structures of fuels like methanol and ethanol and compare them to gasoline, which is of great interest to DISI engines. Three different temperatures of 50, 100, and 200°C and two chamber pressures, 4 and 8 bar, are considered to simulate typical engine-cylinder conditions. It is observed that the initial chamber conditions greatly influence the spray structure. Spray collapse is lesser for alcohol than gasoline. Three semi-empirical models for predicting spray penetration are analyzed: Dent, Hiroyasu and Arai, and Arrègle. These models could not differentiate between the test fuels, particularly methanol and ethanol, for predicting spray penetration length. The degree of deviation in predictions is the lowest in the Hiroyasu and Arai model and the highest in the Dent model. Spray penetration length increased with an increasing FIP regardless of ambient conditions; however, the spray penetration length decreased with increasing chamber pressure.

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DROPLET SIZE DISTRIBUTION PARAMETERIZATION FOR FLAT FAN SPRAYS OF AGRICULTURAL TANK MIXTURES

In agricultural spray application of pesticides, the volumetric droplet size distribution (VDSD) critically influences the efficacy of the application as well as the risk of off-target spray deposition. It is critical to have accurate predictions of the VDSD for development of new agrochemicals and spray nozzles. VDSD parameterization and subsequent prediction is complicated in agrochemical sprays by the unique geometries of the nozzles employed, which typically do not have clearly evident hydraulic diameters and vary in size, as well as by the effects of active herbicides and adjuvants on the spray. Herein, scaling based on conservation of energy is utilized to develop a relationship predicting the VDSD for flat fan sprays used in agrochemical application with agrochemical products. To examine the proposed scaling relationship, we made measurements of VDSDs using laser diffraction interferometry for agriculturally relevant tank mixtures, including active pesticides and both emulsion-forming and rheology-modifying drift control adjuvants, sprayed with complex geometry, flat fan nozzles typical of field application. We show that for three distinct nozzle types and three tank mixtures (nine combinations), VDSDs can be normalized by the Sauter mean diameter (<i>D<sub>32</sub></i>), and normalized distributions collapse for given nozzle type-spray tank mix combination. Subsequently, we show for all test combinations that the Sauter mean diameter normalized by the nozzle hydraulic diameter (<i>D<sub>H</sub></i>) scales with the ratio of product of tank mix surface tension and hydraulic diameter divided by the nozzle pressure drop, with a scaling exponent of 1/3.

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INFLUENCE MECHANISM OF STAGNATION-POINT FLOW ON LIQUID-PHASE SPRAY PENETRATION LENGTH UNDER ENGINE-LIKE CONDITIONS

Formulation of liquid-phase spray penetration length (LPL) is one of the basic research works of direct injection (DI) engines. To predict the spray evolution and LPL in the limited space more accurately, the diffused background-illumination extinction imaging (DBI) technology and highspeed schlieren method were employed to detect the liquid- and vapor-phase spray development in a constant volume combustion chamber (CVCC). The experimental results show that the LPL of the impinging spray is significantly smaller than that of the free spray when the LPL is close to the impinging distance. When the LPL is much smaller than the impinging distance, the LPL of impinging spray is the same as that of free spray. Furthermore, based on the CFD simulation and the stagnation-point flow theory, the spatial distribution of velocity, pressure, and density at the near-wall surface was analyzed in detail. Due to part of the spray kinetic energy was converted into potential energy, creating a sharp increase in pressure and density near the stagnation point, which suppressed the movement of fuel droplets, resulting in a significantly smaller LPL. Moreover, a novel LPL prediction model is introduced, which considering the inhibiting effect of wall on spray penetration and demonstrates enhanced predictive capability of experimental results.

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ATOMIZATION CHARACTERISTICS OF AN ANNULAR SHEET WITH INNER AIR IN A SONIC TWIN-FLUID ATOMIZER

This study examines the sonic twin-fluid atomizer based on gas-dynamic effects and atomization behavior with two distinct configurations: converging and converging-diverging (CD) atomizers. The atomization characteristics are compared by employing a 280-<i>μ</i>m annular liquid sheet with central core air. CD atomizer exhibited the sheet rupture breakup mechanism, whereas perforated wavy sheet disintegration was observed in the converging atomizer with both atomizers exhibiting a bursting phenomenon. Sauter mean diameter (<i>D</i><sub>32</sub>) slightly varied with increased axial locations in the turbulent region. In comparison, <i>D</i><sub>32</sub> drastically increased with an increase in radial locations in the aerodynamic region, with more increment in the converging atomizer. Drop size distribution (DSD) showed unimodal distribution with a narrower range for CD atomizer in the turbulent region. In the aerodynamic region, DSD becomes more dispersed with an increase in radial location. The relative span factor (Δ) value sharply decreases for the converging atomizer with the axial location in the turbulent region. In comparison, the RSF (Δ) value remains in a narrow range ( ~ 2-4) for both atomizers in the aerodynamic region. Sauter mean diameter (SMD), when plotted against the air-to-liquid mass ratio for the turbulent and aerodynamic region, exhibited a near-inverse relationship. The relative span factor (Δ) displayed a similar trend except for the aerodynamic region with slight variation for the CD atomizer case.

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