Abstract
Molecule Linkage by Sulfur Chlorides. IX. The Addition Reaction of Sulfur Dichlorides with N‐Allyl‐anilines. A Synthesis for 2‐Chloromethyl‐2,3‐dihydrobenzo‐1,4‐thiazinesReactions of different substituted N‐allyl‐anilines 1 with sulfur dichloride yield 2‐chloromethyl‐2,3‐dihydrobenzo‐1,4‐thiazines 3a–i. The identification of the products was carried out by mass spectroscopy and 1H‐n.m.r.‐spectroscopy. The seven‐membered cyclic isomers of the S, N‐heterocycles 3, dihydro‐benzo‐1,5‐thiazepanes 5 were not obtained.
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