Abstract
ZnO encapsulants with capsular configurations (e.g. a large inner cavity, sizeable pore, low density and high specific surface area) have attracted considerable attention as effective and promising candidates in various fields owing to the merits of ZnO (e.g. UV protection, photoelectric catalysis, gas sensitivity, antibacterial effect). However, the research on ZnO encapsulants has not yet reached the eruptive stage. This probably due to their high morphological flexibility and relatively low structural strength that is not easy to control during the preparation process. In this review, the principles of cavity-generating and pore-forming are firstly discussed in depth after going through the synthesis of hollow ZnO in the past ten years. Moreover, the regulation of cavity diameter and pore size of different synthetic strategies is investigated. Then, the research progress of ZnO encapsulants is debated in detail from the loading and release of functional materials and the corresponding characterization. Finally, some potential designs and new views on the future research and development of ZnO encapsulants are concluded.
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