Abstract
have been developed for therearrangement of epoxides to carbonyl compounds. How-ever, there has been little success in the selective rearrange-ment of epoxides, being plagued by the formation ofbyproducts and low yield.In studying the carboxylation of sterically hindered ep-oxides, we have found that in the absence of carbon dioxidethese epoxides rearranges to carbonyl compounds. Forexample,
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