Abstract

The electrochemical properties of β-Zn 4Sb 3 and Zn 4Sb 3C 7 as new lithium-ion anode materials were investigated. The reversible capacities of the pure Zn 4Sb 3 alloy electrode and 100 h milled Zn 4Sb 3 in the first cycle reached 503 and 566 mA h/g, respectively, but the cycle stability of Zn 4Sb 3 whether milled or not were obviously bad. It was demonstrated that cycle stability of Zn 4Sb 3 could be largely improved by milling after mixing with graphite. It was shown that Zn 4Sb 3C 7 composite has a lithium-ion extraction capacity of 581 mA h/g at the first cycle and 402 mA h/g at 10th cycle.

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