Abstract
Though fluorescence-tag-based anti-counterfeiting technology has distinguished itself with cost-effective features and huge information loading capacity, the clonable decryption process of spatial-resolved anti-counterfeiting cannot meet the requirements for high-security-level anti-counterfeiting. Herein, we demonstrate a spatial-time-dual-resolved anti-counterfeiting system based on new organic-inorganic hybrid halides BAPPZn2 (Cly Br1-y )8 (BAPP=1,4-bis(3-ammoniopropyl)piperazinium, y=0-1) with ultra-long room-temperature phosphorescence (RTP). Remarkably, the afterglow lifetime can be facilely tuned by regulating the halide-induced heavy-atom effect and can be identified by the naked eyes or with the help of a simple machine vision system. Therefore, the short-lived unicolor fluorescence and lasting-time-tunable RTP provide the prerequisites for unicolor-time-resolved anti-counterfeiting, which lowers the decryption-device requirements and further provides the design strategy of advanced portable anti-counterfeiting technology.
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