Abstract
Hg-based high-temperature superconductors (Hg-HTSs) have a similar layered structure to that in most other superconducting cuprates. The weakly attached Hg cations can be swapped with Tl ones in a cation exchange process, which allows exploration of the physical properties associated closely to the charge reservoir block change as a consequence of the Hg–Tl cation exchange. This paper intends to provide an overview of over a decade long investigation of Hg(Tl)-HTSs thin films processed in forward and reverse cation exchange, and from which to elucidate the interesting aspects that are related to the superconductivity of these fascinating materials.
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