Abstract

Abstract A significant disadvantage of parts made of linear block polyurethanes under conditions of friction contact in the presence of an aqueous medium is the intensification of hydrolysis processes and decrease in volume strength. It was proposed to slow down the hydrolysis of polyurethanes in three ways: by directed changes in chemical structure, by electromagnetic radiation of different intensities and by creation of composite materials, based on the principle of additional intermolecular crosslinking at the manufacturing and hot processing stages. The conditions for the formation of a smooth wear-resistant surface that protects the material from rapid destruction are revealed.

Highlights

  • Polyurethanes are among the most universal and practically used polymers, due to the wide possibilities of changing their chemical structure and properties [1]. They are processed by high-performance injection molding, extrusion, blowing, pneumatic molding, pressing, etc

  • All known types of materials and products can be obtained from polyurethanes: filled, reinforced, foamed, laminated and others in the form of plates, sheets, blocks, profiles, fibers, films, etc

  • Polyblock polyurethanes of linear structure are widely used in industry because of their unique combination of properties: high level of strength and elasticity, oil and gas resistance, resistance to shock loads and vibration

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Summary

Introduction

Polyurethanes are among the most universal and practically used polymers, due to the wide possibilities of changing their chemical structure and properties [1]. They are processed by high-performance injection molding, extrusion, blowing, pneumatic molding, pressing, etc. Polyblock polyurethanes of linear structure are widely used in industry because of their unique combination of properties: high level of strength and elasticity, oil and gas resistance, resistance to shock loads and vibration. Products and constructions based on linear block-polyurethanes (BPU) are used in all industries without exception. Previous studies have shown that the magnitude of wear rate of the oligesters-based BPU when adding water to the contact zone increases more than an order of magnitude [3]

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