Water property variability into a semi-enclosed sea dominated by dynamics, modulated by properties

To control disinfection byproduct (DBP) formation in drinking water, an understanding of the source water total organic carbon (TOC) concentration variability can be critical. Previously, TOC concentrations in water treatment plant source waters have been modeled using streamflow data. However, the lack of streamflow data or unimpaired flow scenarios makes it difficult to model TOC. In addition, TOC variability under climate change further exacerbates the problem. Here we proposed a modeling approach based on local polynomial regression that uses climate, e.g. temperature, and land surface, e.g., soil moisture, variables as predictors of TOC concentration, obviating the need for streamflow. The local polynomial approach has the ability to capture non-Gaussian and nonlinear features that might be present in the relationships. The utility of the methodology is demonstrated using source water quality and climate data in three case study locations with surface source waters including river and reservoir sources. The models show good predictive skill in general at these locations, with lower skills at locations with the most anthropogenic influences in their streams. Source water TOC predictive models can provide water treatment utilities important information for making treatment decisions for DBP regulation compliance under future climate scenarios.

Biogeochemical drivers of changing hypoxia in the California Current Ecosystem

The drinking water for more than 28 million people was screened for a diverse group of pharmaceuticals, potential endocrine disrupting compounds (EDCs), and other unregulated organic contaminants. Source water, finished drinking water, and distribution system (tap) water from 19 U.S. water utilities was analyzed for 51 compounds between 2006 and 2007. The 11 most frequently detected compounds were atenolol, atrazine, carbamazepine, estrone, gemfibrozil, meprobamate, naproxen, phenytoin, sulfamethoxazole, TCEP, and trimethoprim. Median concentrations of these compounds were less than 10 ng/L, except for sulfamethoxazole in source water (12 ng/L), TCEP in source water (120 ng/L), and atrazine in source, finished, and distribution system water (32, 49, and 49 ng/L). Atrazine was detected in source waters far removed from agricultural application where wastewater was the only known source of organic contaminants. The occurrence of compounds in finished drinking water was controlled by the type of chemical oxidation (ozone or chlorine) used at each plant. At one drinking water treatment plant, summed monthly concentrations of the detected analytes in source and finished water are reported. Atenolol, atrazine, DEET, estrone, meprobamate, and trimethoprim can serve as indicator compounds representing potential contamination from other pharmaceuticals and EDCs and can gauge the efficacy of treatment processes.

The increased incidences of disorders of male reproductive tract as well as testicular and prostate cancers have been attributed to androgenic pollutants in the environment. Drinking water is one pathway of exposure through which humans can be exposed. In this study, both potencies of androgen receptor (AR) agonists and antagonists were determined in organic extracts of raw source water as well as finished water from waterworks, tap water, boiled water, and poured boiled water in eastern China. Ten of 13 samples of source water exhibited detectable AR antagonistic potencies with AR antagonist equivalents (Ant-AR-EQs) ranging from <15.3 (detection limit) to 140 μg flutamide/L. However, no AR agonistic activity was detected in any source water. All finished water from waterworks, tap water, boiled water, and poured boiled water exhibited neither AR agonistic nor antagonistic activity. Although potential risks are posed by source water, water treatment processes effectively removed AR antagonists. Boiling and pouring of water further removed these pollutants. Phthalate esters (PAEs) including diisobutyl phthalate (DIBP) and dibutyl phthalate (DBP) were identified as major contributors to AR antagonistic potencies in source waters. Metabolites of PAEs exhibited no AR antagonistic activity and did not increase potencies of PAEs when they coexist.

To help determine the future course of the source water management policies of Seoul, South Korea, this article qualitatively analyzes and compares the existing source water management systems of five large metropolitan areas: Seoul; Chicago, Illinois, and, New York City in the United States; and, Osaka and Tokyo in Japan. New York and Chicago have completely separated systems for source water and wastewater that do not allow wastewater, even treated effluent, to mix with source water. As a result, these cities enjoy source water of the highest quality on a sustainable basis. However, Tokyo and Osaka still struggle with low water quality, even though their wastewater handling capabilities are by no means inferior to those of the American cities. The Japanese cities' water quality problems appear to occur primarily because their systems allow treated effluents and discharges from agricultural and urban nonpoint sources to be mixed into their source water systems. Recently, through programs that build wastewater conveyance aqueducts along sections of the Yodo and Edo rivers, Osaka and Tokyo, respectively, have begun to adopt the concept of separating wastewater from source waters. The authors believe that if Osaka and Tokyo want to further improve their source water quality, they must follow the example of New York and Chicago and expand the concept of separation of systems farther upstream. Seoul has taken a similar approach by trying to separate its primary water and wastewater systems, and then proceed with expanding its waste systems and introducing advanced water treatment processes.

ABSTRACTFeral horse (Equus ferus caballus) populations on public rangelands in the western United States threaten forage production for livestock and wildlife habitat. Interference competition between feral horses and heterospecifics at watering sources can have negative effects on livestock and wildlife. Researchers have documented altered timing and behavior of wild ungulates at water sources when horses were present. The few studies examining these interactions have infrequently occurred within areas specifically managed for feral equids and have not occurred in sites with cattle. We used motion‐sensitive cameras at 8 watering sources to document watering activity patterns and construct indices of temporal overlap among feral horses, cattle, elk (Cervus canadensis), mule deer (Odocoileus hemionus), and pronghorn (Antilocapra americana) within the Adobe Town Herd Management Area in southern Wyoming, USA, between June and September 2018 and 2019. Feral horses, cattle, and pronghorn exhibited a high degree of temporal overlap (&gt;79%) in water use, with feral horses and pronghorn exhibiting the highest estimated percent overlap (88.1%, 95% CI = 86.5–89.6%). Mule deer and elk watering activity also overlapped with horses and cattle but to a lesser degree (&lt;55%). Feral horses spent a mean of 16.7 ± 30.5 (SD) minutes during a watering event and were present at a given water source on average 4.5 ± 6.3% and up to 34.9% of the day, which is less than reported in previous studies. Cattle spent on average 23.5 ± 44.9 minutes during a watering event, and were present on average 4.2 ± 7.7% and up to 42.4% of the day at a single water source. Results of generalized linear mixed‐effects models indicated that number of conspecifics was the strongest predictor of visit duration for pronghorn and horses; hour of the day and group size of heterospecifics were informative, but less important, variables. There was no difference in peak visitation time for any species between sites of high versus low horse or cattle use. Despite temporal overlap, we did not find evidence of interference competition between feral horses, cattle, and pronghorn. We recommend future examination of interference competition and its biological consequences between introduced and native ungulates at water sources of varying size across sites, equid population levels, and livestock stocking rates. © 2020 The Wildlife Society.

Clean hydrogen will require significant volumes of water given the high production targets in certain geographic locations, regardless of generation pathway, i.e., from an electrolyzer or natural gas-based process with carbon capture and sequestration (CCS). Therefore, reliable water sourcing related to the planned infrastructure's location is a critical input that needs to be considered in the early project planning stages. This paper will review the potential sources of water and costs associated with incorporating them within the hydrogen supply chain and will explore the respective attributes of alternatives. Water demand will vary between different hydrogen production methods, site locations, and project specific facility designs. Furthermore, the cost of water will vary as well depending on the source water's respective quality, facilities, water conveyance, treatment, and waste disposal requirements. For the energy industry, water for hydrogen production has become as important as natural gas for its processes and as important as crude oil has been for its refineries. Project viability depends on the long-term reliable access to the selected water source, forcing project siting to be a critical project consideration. Additionally, water treatment processes vary according to the source's base purity and contaminants. Subsequently, these processes create waste streams with concentrated impurities, which may have to be mitigated prior to disposal. We will provide the readers with awareness of the issues related to water sourcing options and considerations, conveyance, and rough order of magnitude (ROM) costs for water infrastructure, including treatment. The clarification of costs associated with different water sources used for hydrogen generation will allow project developers to make more informed decisions. Water sourcing should be a topic at the forefront of planning stages related to hydrogen production. The authors for this paper wish to provide a better understanding of costs related to different options. Additionally, the implementation of circularity will be analyzed by considering recycled wastewater as the water source for a hydrogen plant. This could reduce the regional disparity in clean energy production and lessen the burden on fresh water supplies.

The water that surrounds us lakes, rivers, streams, and aquifers makes up our drinking water sources. These source waters can be threatened by a number of potential sources of contamination, such as on-site septic systems, sewer lines, hazardous chemical storage, storm water runoff, and animal wastes. The determination of the potential or risk is a key component of the source water assessment. The Texas Source Water Assessment and Protection (SWAP) Program was promulgated as part of amendments to the 1996 Safe Drinking Water Act and consists of two fundamental aspects: Assessment and Protection. Source water assessments determine a water supply’s susceptibility to contamination. Source water protection is the implementation of management strategies or practices to mitigate or eliminate risks associated with potential sources of contamination (PSOC). The assessments and protection plan are specific to each public water system, its source waters, and areas of concern which may impact source waters. The objective of this paper is to discuss the innovative methodology used to encourage development of source water protection programs and conduct source water protection activities for selected public water systems using groundwater as the water supply. The methodology includes both technical activities as well as educational and outreach efforts to encourage active participation in the program. This paper will document the process used and present the results of these activities in multiple communities.

Identification of complex septic odorants in Huangpu River source water by combining the data from gas chromatography-olfactometry and comprehensive two-dimensional gas chromatography using retention indices

Adequate water supply is one of the public health issues among the population living in low-income settings. Vibriosis remain a significant health challenge drawing the attention of both healthcare planners and researchers in South West districts of Uganda. Intending to clamp down the disease cases in the safest water deprive locality, we investigated the virulent toxins as contaminants and epidemiologic potentials of Vibrio species recovered from surface waters in greater Bushenyi districts, Uganda. Surface water sources within 46 villages located in the study districts were obtained between June and October 2018. Standard microbiological and molecular methods were used to analyse samples. Our results showed that 981 presumptive isolates retrieved cell counts of 10–100 CFU/g, with, with (640) 65% confirmed as Vibrio genus using polymerase chain reaction, which is distributed as follows; V. vulnificus 46/640 (7.2%), V. fluvialis 30/594 (5.1), V. parahaemolyticus 21/564 (3.7), V. cholera 5/543 (0.9), V. alginolyticus 62/538 (11.5) and V. mimicus 20/476 (4.2). The virulence toxins observed were heat-stable enterotoxin (stn) 46 (82.10%), V. vulnificus virulence gene (vcgCPI) 40 (87.00%), extracellular haemolysin gene {vfh 21 (70.00)} and Heme utilization protein gene {hupO 5 (16.70)}. The cluster analysis depicts hupO (4.46% n = 112); vfh (18.75%, n = 112); vcgCPI and stn (35.71%, & 41.07%, n = 112). The principal component analysis revealed the toxins (hupO, vfh) were correlated with the isolate recovered from Bohole water (BW) source, while (vcgCPI, stn) toxins are correlated with natural raw water (NRW) and open springs (OS) water sources isolates. Such observation indicates that surface waters sources are highly contaminated with an odds ratio of 1.00, 95% CI (70.48–90.5), attributed risk of (aR = 64.29) and relative risk of (RR = 73.91). In addition, it also implies that the surface waters sources have > 1 risk of contamination with vfh and > six times of contamination with hupO (aR = 40, − 66). This is a call of utmost importance to the population, which depends on these water sources to undertake appropriate sanitation, personal hygienic practices and potential measures that ensure water quality.

Coastal upwelling variability in the California Current region, one of the four main eastern boundary current upwelling systems, is controlled by processes acting over a wide range of spatial and temporal scales. While the ensuing ecosystem response depends strongly on upwelled water properties, determining their exact physical and biogeochemical characteristics is notoriously difficult as it requires tracking water masses backward in space and time from the moment they upwell near the coast to their subsurface origin. Adjoint model simulations have been used successfully to track water masses in coastal upwelling systems and the work presented here extends these applications to determining the co‐variability of physical and biogeochemical properties of source waters at spatial scales that resolve the known alongshore variability of coastal upwelling in the region. Notably, the results identify that the modulation of coastal upwelling efficiency by onshore/offshore geostrophic meanders is the dominant mechanism explaining alongshore variability in source depth and properties of upwelled waters. The simulations also reveal that source water properties vary seasonally in response to different balances between coastal upwelling intensity and biogeochemical processes. During spring, interannual variability of physical and biogeochemical properties is directly tied to the intensity of upwelling‐favorable alongshore winds, whereas, during summer, biogeochemical properties respond more strongly to biological activity and subsequent organic matter remineralization at depth. Overall, the present work provides important insight into the mechanisms responsible for the alongshore mosaic and seasonal variation of upwelled source water properties in the central California Current region.

Natural dumpflood injection is used for pressure maintenance in a good channel sand holding considerable reserves. The layer is on depletion drive with very weak aquifer support. Natural dumpflood injection was modeled based on success in a similar layer in an adjacent field. Due to the high mud weight used during drilling, the layer is usually damaged. Dumpflooding experience in the analogue field suggests that injection is initiated only after matrix acid stimulation. Therefore, it was not a surprise when the layer did not take in any water initially. However, once the usual stimulation attempts did not achieve the desired results, possible causes and alternates were evaluated. A comprehensive lab study was designed to assess all the potential problems associated with injection. Fluid-fluid interaction issues like scaling, possible formation of oil-in-water emulsion, fluid-rock interaction such as clay swelling, fine migration related to water incompatibility, all impacting efficiency of water injection on oil mobility and recovery were studied. To simulate every possible field condition all the major water sources were sampled and taken for study. For fluid rock interaction studies, core plugs from the layer was used. Scale tendency was studied using Jar test and predictions at reservoir conditions were made through ChemScale software. The scaling products from Jar test was analyzed with SEM confirming the results. Routine core analysis was performed to measure porosity and permeability in the coreplugs. XRD was done to understand the mineralogy of the layer. After measuring the baseline permeability, the plugs were subjected to flooding with source waters. One set of coreplugs were fully saturated with target water and flooded with source waters. Flooding was repeated on core plugs saturated with oil at irreducible water saturation until it reached residual oil saturation. An investigation of emulsion formation was conducted between oil and source waters. Study results gave an indication of many potential issues like self scaling tendency of source waters and permeability reduction due to fine migration and scale formation. Out of the many factors, the presence of considerable concentrations of sulphate forming cations was identified as the primary issue to focus on. Sulphate reducing chemicals are being evaluated for injection along with the source water. Injection water quality is one of the primary factors to consider for effective injection. This is even more crucial in case of dumpflooding, wherein water is sourced from sub-surface. Due to the wide extent of the field and possible diagenesis effect there could be regional variations in water quality. Due diligence needs to be paid to these regional variations in water quality and choose prudently among alternate source water reservoirs.

Mangrove ecosystems rely on seawater, rain-derived flow, and groundwater for hydrologic sustenance, flushing, and inflow of nutrients and sediments. The relative contribution of these source waters and their variability through time and space can provide key information concerning the hydrologic function of ecosystems. We used hydrologic tracers to partition source waters and trace their movements in the Enipoas stream, a river-dominated mangrove ecosystem on the island of Pohnpei, Federated States of Micronesia (FSM) and in the Yela watershed, an interior mangrove ecosystem on the island of Kosrae, FSM. The Enipoas site was characterized as a salt wedge estuary whose source water contributions alternated between predominantly seawater and rain-derived flow, depending on the tide. The source waters in the interior Yela site were also predominantly seawater and rain-derived flow, however the relative contribution of each was much more stable. The mean groundwatercontribution was 5% (SD 5 5.5) for the Enipoas site and 20% (SD 5 11.0) for the Yela site. Although a small contributor to flow, groundwater was a steady source of freshwater for both systems. Hydrologic linkages between mangroves and adjacent ecosystems were demonstrated by the temporal and spatial distribution of source waters.The 0.8 km Enipoas estuary, with its highly dynamic bi-directional flows, transported source waters along a hydrologic continuum comprised of coral reef, mangroves, and palm forest. In the interior mangroves of the Yela watershed, the presence of rain-derived flow and groundwater demonstrated a hydraulic connection between the mangroves and an upstream freshwater swamp. Interior mangroves with such linkages avoid stresses such as desiccation and heightened salinity, and thus are more productive than those with little or no freshwater flows.

Post-hydrothermal liquefaction wastewater (PHW) is a byproduct of the hydrothermal liquefaction (HTL) process. Previous research indicates that PHW is free of pathogens and contains nutrients needed for crop growth, but may contain metal(loid)s. This study evaluated the ability of differentially treated PHW for effective and safe hydroponic lettuce production. Water containing only hydroponic fertilizer (Source Water 1) had the highest total dry yield of all five treatments; 3.1 times higher than Source Water 2 (diluted PHW with sand filtration), 3.5 times higher than Source Water 3 (diluted PHW with sand + carbon filtration), 2.6 times higher than Source Water 4 (diluted and nitrified PHW with sand filtration), and 1.3 times higher than Source Water 5 (diluted PHW supplemented with hydroponic fertilizer). Findings also indicated that while PHW was below the US Department of Agriculture Foreign Agriculture Service maximum levels for cadmium, lead, and mercury in food, the concentration of arsenic was 1.6, 2.4, and 2.0 times higher than the maximum level for Source Waters 2, 3, and 4, respectively. There was no detectable E. coli or fecal coliforms in any of the treated PHW. While nitrogen was present in the raw PHW, only 0.03% was NO3-N and NO2-N. Diluted PHW supplemented with hydroponic fertilizer had lower lettuce yield than hydroponic fertilizer alone, indicating a potential non-nutrient inhibition of plant growth by PHW. Therefore, this research demonstrates that treated PHW does not pose a biological contamination risk for lettuce, but may entail levels of arsenic in edible leaf tissues that are in excess of safe levels. Additional treatment of PHW can benefit crop production by allowing crop utilization of a greater fraction of total nitrogen in the raw PHW.

During a cyanobacterial harmful algal bloom (HAB) event, drinking water treatment systems face the challenge of balancing acute and chronic health risks by treating the potentially toxin‐producing HAB and simultaneously managing for disinfection byproduct (DBP) formation. To explore the relationship between HAB events and DBP formation, a unique full‐scale study, including paired source water and finished water monitoring, was conducted at five drinking water utilities with HAB‐impacted source waters. Results confirm bench‐scale findings that HAB events in source water contribute to increases in DBP precursors. However, unlike results from laboratory studies, source water HAB‐related parameters and finished water DBPs were not consistently correlated at the five study utilities. These different outcomes suggest regulated DBP formation in utilities with HAB‐impacted source water is complex and influenced by a variety of site‐specific conditions, including source water conditions and data available for operational decision‐making, timing of treatment adjustments, and key operational choices.