Abstract
In the title compound, C12H9Cl2NO3, which is the fungicide vinclozolin, the dihedral angle between the oxazolidine ring mean plane [r.m.s. deviation = 0.029 Å] and the benzene ring is 77.55 (8)°. In the crystal, molecules are linked via C—H⋯O hydrogen bonds, forming chains along [010]. The chains are linked by short Cl⋯Cl contacts [3.4439 (3) and 3.5798 (3) Å], resulting in a three-dimensional architecture.
Highlights
In the title compound, C12H9Cl2NO3, which is the fungicide vinclozolin, the dihedral angle between the oxazolidine ring mean plane [r.m.s. deviation = 0.029 A ] and the benzene ring is 77.55 (8)
Molecules are linked via C—HÁ Á ÁO hydrogen bonds, forming chains along [010]
The chains are linked by short ClÁ Á ÁCl contacts [3.4439 (3) and 3.5798 (3) A ], resulting in a three-dimensional architecture
Summary
Received 30 May 2014; accepted 2 June 2014Edited by J. Key indicators: single-crystal X-ray study; T = 173 K; mean (C–C) = 0.004 A; R factor = 0.042; wR factor = 0.115; data-to-parameter ratio = 12.9. C12H9Cl2NO3, which is the fungicide vinclozolin, the dihedral angle between the oxazolidine ring mean plane [r.m.s. deviation = 0.029 A ] and the benzene ring is 77.55 (8). Molecules are linked via C—HÁ Á ÁO hydrogen bonds, forming chains along [010]. The chains are linked by short ClÁ Á ÁCl contacts [3.4439 (3) and 3.5798 (3) A ], resulting in a three-dimensional architecture. Related literature For information on the toxicity and fungicidal properties of the title compound, see: van Ravenzwaay et al (2013); Pothuluri et al (2000). For a related crystal structure, see: Merino et al (2010).
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