Abstract
The Raman and infrared spectra of dimethylformamide (DMF)/polyacrylonitrile (PAN) /lithium perchlorate have been measured and analyzed. It is found that the interaction between DMF and PAN is not strong, probably resulting from the dipole interaction between the O=C‒N group of DMF and the nitrile group of PAN. Compared with the Raman spectra of DMF/ system, it seems that the addition of PAN promotes the ion association between ions and the plasticizer molecules. However, in spite of the wide range of molar ratios of DMF/PAN/ studied, no ion association was observed between the nitrile group of PAN and the ions in the DMF/PAN/ system. This indicates that the details of the transport mechanism of ions in the electrolyte may be related to the plasticizer.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
