Abstract
The Raman and IR spectra are reported for the complexes ZnCl 2.2TMPO, ZnBr 2.2TMPO and ZnI 2.2TMPO. The observed frequencies for polycrystalline samples are assigned on the basis of a C 3v structure for the TMPO ligand and a C 2y structure for the ZnX 2O 2 skeletal fundamentals. To discuss the coordination effects of TMPO, the ligand vibrations are compared with those of free TMPO and the skeletal vibrations with those of acetonitrile complexes. Using the ratios of G matrix elements and of observed frequencies for symmetric and asymmetric Zn-X stretching modes, the ZnX 2O 2 skeletal structures are found to be tetrahedral.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
