Abstract
The IR and Raman spectra of methyl- d 3 vinyl and methyl- d 3 vinyl- d 3 ethers are reported (along with earlier published spectra of the undeuterated molecule). The normal coordinate analysis, based upon CNDO/2 force constant calculations, confirms the absence of significant changes in CH 3 group dynamical properties in methyl vinyl ether compared to saturated ethers. Normal coordinate calculations of possible rotamers ( cis structure force field with certain assumptions has been used) favours the planar trans (or close to it) structure of the second isomer.
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