Abstract

The variations of the mechanical properties of the CoCrFeMnNi high entropy alloy (HEA) during groove cold rolling process were investigated with the aim of understanding their correlation relationships with the crystallographic texture. Our study revealed divergences in the variations of the microhardness and yield strength measured from samples deformed by groove cold rolling and conventional cold rolling processes. The crystallographic texture analyzed by electron back scattered diffraction (EBSD) revealed a hybrid texture between those obtained by conventional rolling and drawing processes. Though the groove cold rolling process induced a marked strengthening effect in the CoCrFeMnNi HEA, the mechanical properties were also characterized by an unusual decrease of the Young’s modulus as the applied groove cold rolled deformation increased up to about 0.5 before reaching a stabilized value. This decrease of the Young’s modulus was attributed to the increased density of mobile dislocations induced by work hardening during groove cold rolling processing.

Highlights

  • Both microhardness and yield strength displayed a strong increase with the strain up to ε = 0.5 by groove cold rolling followed by a moderate increase, to reach values of, respectively, around 400 HV and 1400 MPa for an applied groove rolling deformation ε equal to 2.2

  • It has been assumed that the deformation mechanisms involved during groove cold rolling were the same as those already reported for CoCrFeMnNi high entropy alloy (HEA) alloy, i.e., dislocation glide and twinning

  • Samples of CoCrFeMnNi HEA were successively deformed by groove cold rolling at different strain levels

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Summary

Introduction

High entropy alloys (HEAs), a new class of metallic materials in which the stability of the solid solution is explained by contribution of the configurational entropy, have recently received particular attention, owing to the prospect of developing new systems with tailored properties suitable for a large range of different applications from dies and molding materials to corrosion-resistant coatings in manufacturing, energy, transport, and aeronautical industries [1,2,3,4].The stabilization of the solid solution is associated to special features such as low diffusion kinematics, lattice distortion and “cocktail effect” whose effects have been discussed in the literature [1,3,5].The equi-atomic CoCrFeMnNi composition developed by Cantor and colleagues [6] is currently one of the most studied HEA. High entropy alloys (HEAs), a new class of metallic materials in which the stability of the solid solution is explained by contribution of the configurational entropy, have recently received particular attention, owing to the prospect of developing new systems with tailored properties suitable for a large range of different applications from dies and molding materials to corrosion-resistant coatings in manufacturing, energy, transport, and aeronautical industries [1,2,3,4]. Materials 2018, 11, 1337 alloys against those of conventional solid solution alloys Some key studies, such as those published by Wu et al [10] and Laurent-Brocq and co-workers [11,12], already helped in the understanding the formation of these solid solutions, the influence of each constituent element on the stability of the microstructure. Examinations of the deformation mechanisms have demonstrated that deformation occurred mainly by dislocation glide and sub-cell creation [8,18]

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