Abstract

Green and red rusts are formed when iron is partially or completely oxidised. Analogues of the rusts may be precipitated from iron(II) and iron (III) salt solutions treated with alkali under reducing or oxidising conditions. Variations in surface area and porosity have been investigated by gravimetric nitrogen gas sorption, using vacuum microbalance techniques. Freshly-precipitated red rusts, hydrous iron (III) oxide, have surface areas of about 200–400 m 2g −1. When they are added to iron (II) hydroxide suspensions kept at pH 7, the green Fe (II)-Fe (III) rusts formed have lower surface areas of about 40–100 m 2g −1, depending on the initial iron(II) sulphate concentrations.

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