Abstract
The following substituted magnesium chloride hexa-ammines: 24Mg( 14NH 3) 6Cl 2; 26Mg( 14NH 3) 6Cl 2; 24Mg( 15NH 3) 6Cl 2; 24Mg( 14ND 3) 6Cl 2; 24Mg( 14ND 3) 6Cl 2 have been studied by i.r. and Raman spectroscopy. The frequency shifts have been measured for all active vibrational bands predicted by group theory analysis. The results show that measurements made on isotopically substituted compounds can provide confirmation of assignments of vibrational bands previously proposed [2].
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