Abstract

Large-scale molecular orbital balloon models have been designed and developed for implementation in the general, organic, or physical chemistry classroom. The purposes of the models are to help students visualize and understand concepts of pi-bonding, conjugation, aromaticity, and cycloaddition reactions or symmetry-controlled reactions. Second-semester organic chemistry students have welcomed the models with positive responses, claiming that the 3D models bring 2D textbook and lecture images to life. The balloon models may be constructed and presented by the instructor during a formal lecture, or they may be constructed by students during problem-solving workshops. Short video tutorials have been created to demonstrate the construction of these inexpensive classroom manipulatives.

Highlights

  • Why Balloons? Our student affiliate chapter of the American Chemical Society [1] successfully uses balloons for public outreach and fundraising activities

  • By using 260 modeling “twist” balloons and 5-inch round balloons, [11] tangible models can be quickly constructed in class to help students visualize the concepts of pi-bonding, conjugated systems, and molecular orbital (MO) theory (Figure 1)

  • A cis alkene model can quickly be repositioned into a trans alkene, but the pi bond must be broken in the process. (Figure 2 a & b)

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Summary

Introduction

Our student affiliate chapter of the American Chemical Society [1] successfully uses balloons for public outreach and fundraising activities. Balloons do not require much storage room, but when they are inflated, they are large enough to see from a great distance. There have been many papers published regarding the use of balloons as an aid in teaching various chemical concepts. [6] Balloons have been used teach VSEPR theory, [7] atomic orbitals, [8] and the modeling of organic molecules. [9] Balloons of different shapes and sizes are readily available at party stores, large retail stores, and online venders [10] The ever-popular hydrogen balloon explosion. [6] Balloons have been used teach VSEPR theory, [7] atomic orbitals, [8] and the modeling of organic molecules. [9] Balloons of different shapes and sizes are readily available at party stores, large retail stores, and online venders [10]

Orbital Models
Pi-Bonding
Pi-Conjugated Systems
Cis and Trans Alkenes
Frontier-Molecular Orbital Theory
Electrocyclic Reactions
Student Responses
Conclusions
Findings
Associated Content
Full Text
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