Abstract
Uranyl(VI) nitrate, chloride, and perchlorate complexes with the cyclic polyethers dibenzo-18-crown-6 and benzo-15-crown-5 have been synthesized. The compounds have been characterized by elemental analyses, molar conductances, infrared and electronic spectra, and thermal analyses. The infrared and conductivity data, together with a consideration on the general coordination behaviour of the uranyl ion, suggest that the uraniun is not located at the center of the cyclic ligand.
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