Ultrasonic assisted enhanced catalytic effect of perovskite to promote depolymerization of lignin

Abstract

The search for renewable energy sources to replace fossil fuel has made lignin a promising carbon-containing resource. In this paper, LaNiO3 perovskite catalyst supported by mesoporous carrier with specific pore structure was prepared by the pore filling of MCM-41 with citrate complex precursors of nickel and lanthanum. Then the catalysts applied to maize straw lignin depolymerization. The results of low-angle XRD, N2 adsorption-desorption, IR spectroscopy and SEM confirmed that the catalyst has been successfully manufactured. Based on the yield of phenolic monomer, low molecular weight lignin derived bio-oil and high molecular weight lignin derived bio-oil as standard, the catalyst showed best catalytic effect when the reaction temperature was 250 °C, the reaction time was 6 h, the ratio of lignin to catalyst mass was 5: 1 and with ultrasonic assist. The yield of phenolic monomer was 11.46 wt% and that of bio-oil was 68.0 wt%. In general, this method is an excellent embodiment of the principle of Lignin-first as well as an excellent strategy for the production of value-added phenolics and high-quality bio-oils from lignin. It plays an important role in promoting the high value utilization of lignin in the future.