Abstract
Viscosity control and reactivity enhancement are critical to produce high-quality cellulose products, such as dissolving pulp, yet remain challenging. In this work, an ultrafast process, namely microwave-assisted deep eutectic solvent (MW-DES), is proposed for this purpose. It is based on the hypothesis that the MW-DES process can deliver an enhanced synergy: a simultaneous fiber swelling and cellulose depolymerization via hydrogen-bonding break-up and acid hydrolysis from the actions of polar and acidic DES further boosted under MW irradiation. Results showed that after the MW-DES (Choline chloride- oxalic acid, ChCl-OA) treatment for only 40 s, the pulp viscosity decreased from 715 to 453 mL/g, and the reactivity increased from 43.0 % to 84.6 %, which is ultrafast in comparison with those reported work. Furthermore, DES in the process shows a high reusability and chemical stability, thus offering a simple, sustainable and effective alternative for upgrading of dissolving pulp, particularly, using non-wood materials of bamboo.
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