Abstract
The self-assembly of two-dimensional arrays of molecules on surfaces using supramolecular chemistry offers opportunities for the development of new low-dimensional materials and intriguing host–guest chemistry. The growth of these novel materials requires efficient strategies for positioning molecules in specific sequences and supramolecular chemistry offers attractive pathway strategies for the design of such systems. This article focusses on how intermolecular interactions can be exploited to control supramolecular organization on surfaces, demonstrating the use of hydrogen bonds and other intermolecular interactions to construct low-dimensional structures on surfaces.
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