Two-step synthesis of sulfur/graphene composite cathode for rechargeable lithium sulfur batteries

Abstract

Sulfur/graphene composites with different sulfur contents were prepared by two-step synthesis, where graphene was regarded as a carrier of sulfur active substance. The surface structure and crystal form of the composites obtained were characterized and compared by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). It was found that sulfur was partially coated by graphene. The graphene folds provided more nano-pores and electron transport channels for sulfur. From TGA results, the sulfur contents of the sulfur/graphene composites measured were about 42.32 wt%, 54.94 wt%, and 65.23 wt%. Electrochemical tests demonstrated that sulfur/graphene composite (x=54.94 wt%) cathode exhibited better capacity retention (40.13%) compared with the pure cathode (20.46%), where an initial discharge capacity was up to 1 500 mAh·g−1 and it remained about 600 mAh·g−1 after 30 cycles. Furthermore, the electrochemical reaction mechanism and the state of reaction interface for Li/S battery were analyzed by cyclic voltammogram and AC-impedance spectra. The results indicated that the sulfur/graphene composite with a sulfur content of 54.94 wt%, based on a two-step synthesis, contributed to improving electrochemical properties of lithium/sulfur battery