Abstract
Dimolybdenum(III) edge-sharing bioctahedral (ESBO) complexes, Mo2X6(dtbppm)2 [dtbppm = bis(di(4-tert-butylphenyl)phosphinomethane), X= Cl, Br, I], photoreact when irradiated with near-UV light, cleanly producing the corresponding quadruple metal–metal bonded complexes, Mo2X4(dtbppm)2.
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