Abstract
Ion-neutral complexes (INCs) are intermediates extensively existing in gas-phase ionic reactions. Tandem mass spectrometry (MS(n) ) analysis of indolyl benzo[b]carbazoles was performed on an electrospray ionization quadrupole time-of-flight (ESI-Q-TOF) mass spectrometer in positive ion mode. Two competing INC-mediated reactions were obtained in the fragmentation of protonated indolyl benzo[b]-carbazoles. This study enriches our knowledge of the important roles of INCs in the dissociation of indole compounds in the gas phase. Copyright © 2016 John Wiley & Sons, Ltd.
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