Abstract

We report here the compositional dependency of face-centered cubic (FCC) to hexagonal close-packed (HCP) martensitic transformation in FeMnCo medium entropy alloys (MEAs) and insights into the underlying transformation mechanisms. To this end, we designed MEAs with the same Fe-to-Mn ratio and explored the phase stability therein. Higher Co content was found to facilitate the FCC-HCP transformation kinetics. In situ electron backscatter diffraction studies underpinned an FCC-HCP-(new)FCC transformation chain and its underlying atomistic mechanisms were directly explored via aberration-corrected scanning transmission electron microscopy.

Highlights

  • The mechanical benefits of this athermic transformation are well-documented:15–17 It increases strain hardenability and, thereby, promotes homogenous plastic deformation

  • We report here the compositional dependency of face-centered cubic (FCC) to hexagonal close-packed (HCP) martensitic transformation in FeMnCo medium entropy alloys (MEAs) and insights into the underlying transformation mechanisms

  • In situ electron backscatter diffraction studies underpinned an FCC-HCP-(new)FCC transformation chain and its underlying atomistic mechanisms were directly explored via aberration-corrected scanning transmission electron microscopy

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Summary

Introduction

The mechanical benefits of this athermic transformation are well-documented:15–17 It increases strain hardenability and, thereby, promotes homogenous plastic deformation. Scitation.org/journal/apl transformation,19,27 Co exhibits peculiarity because of the absence of body-centered cubic (BCC) structure in the phase diagram.28 understanding towards its role in affecting the strain-induced FCC-HCP martensitic transformation for concentrated Fe-Mn alloys is lacking.

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