Abstract
The cations and anions of the title salt, 3C6H16N+·HSO4 −·SO4 2−, are linked by N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional network. The hydrogensulfate ion, with a single S—O(H) bond of 1.563 (2) Å, forms a short O—H⋯O hydrogen bond [O⋯O = 2.609 (2) Å] to the sulfate ion. The hydrogensulfate ion accepts two hydrogen bonds from two cations, whereas the sulfate ion, as an acceptor, binds to four cations. The sulfate ion is disordered approximately equally over two sites related by rotation around one of the O—S bonds.
Highlights
Structure Reports OnlineKey indicators: single-crystal X-ray study; T = 295 K; mean (C–C) = 0.004 A; disorder in main residue; R factor = 0.050; wR factor = 0.122; data-to-parameter ratio = 18.8
The cations and anions of the title salt, 3C6H16N+ÁHSO4ÀÁSO42À, are linked by N—HÁ Á ÁO and O—HÁ Á ÁO hydrogen bonds into a three-dimensional network
The sulfate ion is disordered approximately over two sites related by rotation around one of the O—S bonds
Summary
Key indicators: single-crystal X-ray study; T = 295 K; mean (C–C) = 0.004 A; disorder in main residue; R factor = 0.050; wR factor = 0.122; data-to-parameter ratio = 18.8. The cations and anions of the title salt, 3C6H16N+ÁHSO4ÀÁSO42À, are linked by N—HÁ Á ÁO and O—HÁ Á ÁO hydrogen bonds into a three-dimensional network. The hydrogensulfate ion, with a single S—O(H) bond of 1.563 (2) A , forms a short O—HÁ Á ÁO hydrogen bond [OÁ Á ÁO = 2.609 (2) A ] to the sulfate ion. The hydrogensulfate ion accepts two hydrogen bonds from two cations, whereas the sulfate ion, as an acceptor, binds to four cations. The sulfate ion is disordered approximately over two sites related by rotation around one of the O—S bonds
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
