Abstract

Überraschendes von einem Klassiker: Die Erforschung der (C5Me4H)−-Chemie von Sc-, Y- und Lu-Metallocenen führte zum ersten Bis(η5)-(η1)-koordinierten Tris(polyalkylcyclopentadienyl)-Komplex und zu einer für Polyalkylcyclopentadienyle neuartigen Koordinationsweise über drei Atome (siehe Schema).

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