Abstract

The tribological behavior of novel 7.5 wt% carbon nanotube-based lubricant greases in PAO (polyalphaolefin) oil with and without 1.0 wt% MoS2, together with several other commercial greases such as calcium, lithium, were studied. The test results showed a marked reduction of frictional coefficient achieved by the CNTs based grease samples with an average benefit of around 30% compared to conventional greases. The steady state test under 1.00 GPa average contact pressure in a mixed lubrication regime and the fretting test showed the best results in terms of friction reduction obtained by CNTs greases. Steady state tests at higher average contact pressure of 1.67 GPa proved to have a lower friction coefficient for CNTs grease containing MoS2; otherwise CNTs grease without MoS2 showed an average value of CoF comparable to calcium and lithium greases, both in a boundary and a mixed regime. The protection against wear, a considerable decrease (−60%) of reference parameter was measured with CNTs grease with MoS2 (NLGI 2) in comparison with the worst conventional grease and −22% in comparison with the best conventional grease. The data indicated that our novel carbon nanotube greases show superior tribological properties and will have promising applications in the corresponding industry.

Highlights

  • Most of the failures and energy losses of mechanical systems are due to friction and wear, so lubrication could be considered one of the most effective ways to reduce surface damage and energy dissipations

  • By comparing SEM-XRD spectra collected on the worn surface of the steel ball specimen after tribological tests with conventional greases and carbon nanotubes (CNTs) based grease, a significant difference in carbon content was found on the steel surface

  • The test results showed a marked reduction of frictional coefficient achieved by the CNTs based grease samples with an average benefit of around −30% compared to conventional greases

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Summary

Introduction

Most of the failures and energy losses of mechanical systems are due to friction and wear, so lubrication could be considered one of the most effective ways to reduce surface damage and energy dissipations. As nanomaterials are of growing interest for lubricating systems, more and more attention has been given to carbon nanotubes (CNTs) Their tubular structure exhibits excellent mechanical characteristics (i.e., high tensile strength, high elastic modulus [13,14], high thermal and electrical conductivity [15,16,17,18]) and good lubrication properties, enhancing wear and coefficient Friction (CoF) reduction [19]. In the last few years, the use of carbon nanotubes as additives in lubricating oil/grease has increased, and many research studies have proved that CNTs, with the single-wall (SWCNT) or multi-wall (MWCNT) structure, can improve the tribological performances of the lubricant significantly, compared to a traditional one. The tribological behavior has been investigated in steady-state and fretting sliding conditions, and performance comparisons have been conducted with commercial calcium and lithium greases

Materials
Grease Fabrication
Tribological Characterization
95 N was applied to attain
Tribological Results
Friction coefficient in boundary regime under
Friction coefficient in mixed regime underunder
Surface Analysis Results
Conclusions
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