Abstract
AbstractA novel Ph2P(O)Cl‐mediated direct fluoroalkanesulfinylation of electron‐rich (het)arenes using fluoroalkyl heteroaryl sulfones as the RfSO source (Rf=C4F9, CF2Cl, CF2Br, and CF2COOEt) was developed. This is the first example where 2‐HetSO2Rf performs as the RfSO synthon in organic synthesis via both C(Het)−S and S=O bond cleavage.magnified image
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