Abstract

The transformation of carbon dioxide in aqueous emulsions of perfluorons in the presence of oxygen in the air results in the formation of a mixture of oxalic acid and a minor set of organic compounds C4–C8. The maximum CO2 consumption occurs in the emulsion with the C8F18: H2O vol/vol ratio of 1: 0.42 at pH 2.4; the H2C2O4 yield is 11 mol %.

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