Abstract
Organic (e.g. hydrocarbon) molecules were transferred from one hydrogen bubble stream to another through an aqueous barrier. The transferred molecules were detected by flame ionization detector. Dissolving CD’s or CD-derivatives in the water, the transfer could be facilitated by about one or two orders of magnitude. Non-volatile guest molecules in the solution acted as competitive inhibitors of this “facilitated transport”. Kinetic analysis of the transport and the inhibition provided simple means for estimating the stability constants of CD-complexes for both volatile and non-volatile guest molecules in dilute aqueous solution.
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