Abstract

The asymmetric unit of the title compound, [CuBr2(C6H7N)2], contains one half-mol­ecule, the whole mol­ecule being generated by inversion through a center located at the CuII atom. The geometry around the CuII atom is square planar. Semicoordinate Cu⋯Br bonds [3.269 (1) Å] and nonclassical C—H⋯Br hydrogen bonds connect the mol­ecules, forming chains running parallel to the a axis. These chains are further linked via additional C—H⋯Br hydrogen bonds into a three-dimensional network.

Highlights

  • The asymmetric unit of the title compound, [CuBr2(C6H7N)2], contains one half-molecule, the whole molecule being generated by inversion through a center located at the CuII

  • C—H Br hydrogen bonds connect the molecules, forming chains running parallel to the a axis

  • These chains are further linked via additional C—H Br hydrogen bonds into a threedimensional network

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Summary

Data collection

The asymmetric unit of the title compound, [CuBr2(C6H7N)2], contains one half-molecule, the whole molecule being generated by inversion through a center located at the CuII atom. The geometry around the CuII atom is square planar. C—H Br hydrogen bonds connect the molecules, forming chains running parallel to the a axis. These chains are further linked via additional C—H Br hydrogen bonds into a threedimensional network

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