Abstract
AbstractThe total synthesis of the polyketide antibiotic (−)‐basiliskamide B is described. The convergent asymmetric synthesis relies on the use of a diastereoselective ethyl ketone aldol reaction followed by asynselective reduction of a β‐hydroxy ketone and a Stille cross‐coupling between aZ‐vinylstannane and anE‐vinyl iodide to establish the(Z,E)‐dienamide moiety.
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