Abstract

Three new principles are introduced from the application of group theory to statistical mechanics at thermodynamical equilibrium and in the field-on steady state. They are illustrated with reference to computer simulations in the laboratory frame ( X, Y, Z) and in the molecule fixed frame ( x,y,z) of the point group character tables. The principle governing the effect of applied external fields is illustrated with reference to an applied vortex and shear in conventional and non-equilibrium molecular dynamics computer simulations.

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