Abstract

The flexible four-armed ligand 1,2,4,5-tetrakis(2-pyridylmethylsulfanylmethyl)benzene ( 2tet) was synthesized and reacted with Cd(NO 3) 2 to produce a dinuclear complex. The ligand adopted a folded conformation about the seven and eight coordinate Cd(II) centres and displayed an intramolecular three-layered π-stacking arrangement.

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