Abstract

The Chromatographic behavior of some series of organic selenium compounds and their oxygen and sulfur analogs (urea, thiourea, selenourea; xanthene, thioxanthene, selenoxanthene; xanthone, thioxanthone, selenoxanthone) has been examined by thin-layer chromatography (TLC) on silica gel. The experimental results show the possibility of attaining fast separations on very small amounts of substance (at the microgram level) by simple monodimensional TLC techniques. Urea and its S and Se analogs as well as xanthones are well separated by two- or three-component eluting solvents; xanthenes are not easily screened even by solvent mixtures. The separation of xanthenes from xanthones by the two-dimensional TLC technique is also described. A further result is the possibility of detecting species in trace amounts in the matrix being examined.

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