Thermotropic homopolyesters. III. Preparation and properties of polymers based on 4′‐hydroxyphenyl‐4‐hydroxycinnamate

Abstract

AbstractLow‐molecular‐weight 4′‐acetoxyphenyl‐4‐acetoxyoinnamate, as well as several polyesters synthesized from this monomer and aliphatic dibasic acids, exhibit thermotropic nematic phases. DSC heating curves for all of the polymers exhibit multiple transitions. The amount of crystallinity of these polymers at room temperature is small and the degree of order along the chain axis in the crystalline phase is poor. For the lower homologues the nematic phase exists over a broad temperature range of approximately 100°C. The polyester from chiral (+)‐3‐methyl adipate forms a thermotropic cholesteric phase. Both the diacetoxy monomer and azelate polymers of low molecular weight adopt the homeotropic texture on glass slides, but with increasing molecular weight the planar texture becomes preferred. Investigation of the effects of electric fields in the conduction regime upon the nematic phase of the diacetoxy monomer revealed that Williams domains are formed only with difficulty. In most cases, a stationary pattern appeared instead. At higher voltage the dynamic scattering mode (DSM) was obtained, and above this a field‐induced transition to the isotropic phase. The azelate polyesters exhibited Williams domains and the DSM in the conduction regime. The formation time for Williams domains was fairly short for polymers having ηinh < 0.44 dL/g, but increased to 80 min when ηinh = 0.68 dL/g. The DSM was only observed for polymers having ηinh < 0.61 dL/g. For these polymers the critical frequency separating the conduction and dielectric regimes exhibits a stronger temperature dependence than that of low‐molecular‐weight nematogens. A new instability pattern is reported for the azelate polyesters in the dielectric regime.