Abstract
Abstract Excess volumes of mixing, VE , for binary mixtures of tetrahydrofuran (THF) with 1,2-dichloroethane, 1,1,1-trichloroethane, 1,1,2,2-tetrachloroethane, trichloroethene and tetrachloroethene have been measured dilatometrically at 303.15 K over the entire composition range. Values of VE are negative in all the mixtures except in the system, THF + 1,2-dichloroethane, wherein an inversion in sign of VE is observed. The experimental results are interpreted in terms of molecular interactions.
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