Abstract

The authors have studied thermodynamic conditions for the vapor-phase deposition process in the hot wall epitaxy (HWE) and molecular beam techniques. It was applied to chalcogenides Bi2Te3 and Bi2Se3 which are the main components of thermoelectric devices. After a description of the chemical equilibria involved in the process equilibrium constant, the pressure of the components and the flux were calculated. By comparison with previously published experimental works concerning Bi2Te3 deposition, calculation results appear to be accurate.

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