Thermodynamic properties of nanoparticles during new particle formation events in the atmosphere of North China Plain

Abstract

To better understand the sources, formation, and the transport of air pollutants over North China Plain (NCP), a four-week intensive campaign during summertime in 2014 was conducted in a central NCP rural site. In this study, particle hygroscopicity and volatility measurements were focused to characterize the thermodynamic properties of nanoparticles and gain insight into chemical composition of nanoparticles during the new particle formation (NPF) events. The water-soluble fractions of 30 and 50nm newly formed particles were respectively 0.64±0.06 and 0.61±0.06, indicating that the water-soluble chemical compounds, most likely ammonium sulfate, dominated the condensational growth of newly formed particles over the NCP. Due to containing higher water-soluble fraction, nanoparticles can be activated as cloud condensation nuclei (CCN) at lower supersaturation in the atmosphere of NCP in contrast to cleaner environments, such as Melpitz (Central European background) and Hyytiälä (boreal forest) during the NPF events. Our observations showed that the NPF and subsequent growth significantly resulted in an enhancement in CCN number concentration. The ranges of enhancement factors of CCN number concentration for supersaturation (SS)=0.2, 0.4, 0.8% were respectively 1.9–7.0, 2.7–8.4, and 3.6–10.1. After being heated to 300°C, the shrink factors for 30 and 50nm particles were respectively 0.35 and 0.38. This indicated that non-volatile compounds could be produced during the growth process of newly formed particles.