Abstract
Four component intermacromolecular complexes involving methacrylic acid-acrylamide copolymer, poly(ethylene imine), poly (vinyl pyrrolidone), and poly(methacrylic acid) were prepared. The stability constants and related thermodynamic parameters (e.g. ΔH° and ΔS°) of these complexes were determined at several temperatures. The enthalpy and entropy changes of the systems with temperature have been interpreted in terms of destabilization of the various interacting forces involved in complex formation.
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