Abstract
Kovatś retention indices are used to determine the partial molar free energies of solution of 39 methyl esters of saturated (normal and branched), mono- and poly-unsaturated higher fatty acids in the non-polar phase Se-30 and the polar phase SILAR 5CP. Contributions of double bonds as a function of their number and position in the acid chain to the partial molar free energies of solution (ΔG) are evaluated quantitatively. Linear equations are suggested for the calculation of ΔG of any compounds from their retention indices measured in columns with SE-30 and SILAR 5CP.
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