Abstract
The complexes p-ClC 6H 4AsX 2 · nL (L = pyridine, β- or γ-picoline; X = Cl, Br or I; n = 1, 1.5 or 2) were synthesized and characterized by melting point, elemental analysis, thermogravimetric studies and IR spectroscopy. From the enthalpies of dissolution (in 25 vol. % ethanolic ethanolamine) of the p-chlorophenyldihaloarsines-ligand complexes at 298.15 K, the standard enthalpies (Δ r H ⊖) for the Lewis acid-base reactions were determined. From Δ r H ⊖ values and thermochemical parameters for the arsines and the ligands, standard enthalpies for the complexes were calculated: enthalpy of formation Δ f H ⊖; enthalpy of decomposition Δ D H ⊖; lattice enthalpy Δ M H ⊖; enthalpy of the Lewis acid-base reaction in the gaseous phase Δ r H ⊖(g). The mean standard enthalpies of arsenic-nitrogen bonds were estimated.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
