Abstract
AbstractThe Matsuda theory of cyclic voltammetry for quasi‐reversible reactions is extended to metal dissolution and electrodeposition. Kinetic data can be conveniently obtained from the measurement of peak potentials and peak currents as a function of sweep rate and switching potentials. As an example, the rate constant for the Zn(s)/Zn++ (aq) couple has been measured to be k0 = 7.5 · 10−7 cm s−1.
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More From: Berichte der Bunsengesellschaft für physikalische Chemie
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