Abstract
This paper describes a very general approach to the calculation of the Zeeman splitting effect produced by an external magnetic field on the rotational levels of diatomic molecules. The method is valid for arbitrary values of the total electronic spin and of the magnetic field strength -that is, it holds for molecular electronic states of any multiplicity and for both the Zeeman and incomplete Paschen-Back regimes. It is based on an efficient numerical diagonalization of the effective Zeeman Hamiltonian, which can incorporate easily all the contributions one may eventually be interested in, such as the hyperfine interaction of the external magnetic field with the spin motions of the nuclei. The reliability of the method is demonstrated by comparing our results with previous ones obtained via formulae valid only for doublet states. We also present results for molecular transitions arising between non-doublet electronic states, illustrating that their Zeeman patterns show signatures produced by the Paschen-Back effect.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
